How can miscible liquids that different boiling points be separated
1 answer:
Answer:
By boiling and further condensing the liquid with the lowest boiling point.
Explanation:
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In this case, according to the attached diagram, it turns out possible for us to infer that the mechanism whereby miscible liquids with different boiling points are separated is distillation, because the flask is heated until the boiling point of the liquid with the lowest value, in order to boil it and subsequently condense it, whereas the liquid with the highest boiling point remains in the flask; and therefore, the two liquids are separated.
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Answer:
0.013%
Yes, it does. The answer agrees with the statement.
Explanation:
Both conformers are in equilibrium, and it can be represented by the equilibrium equation K:
K = [twist-boat]/[chair]
The free energy between them can be calculated by:
ΔG° = -RTlnK
Where R is the gas constant (8.314 J/mol.K), and T is the temperature (25°C + 273 = 298 K).
ΔG° = 5.3 kcal/mol * 4.182 kJ/kcal = 22.165 kJ/mol = 22165 J/mol
22165 = -8.314*298*lnK
-2477.572lnK = 22165
lnK = -8.946
K =
K = 1.30x10⁻⁴
[twist-boat]/[chair] = 1.30x10⁻⁴
[twist-boat] = 1.30x10⁻⁴[chair]
The percentage of the twist-boat conformer is:
[twist-boat]/([twist-boat] + [chair]) * 100%
1.30x10⁻⁴[chair]/(1.30x10⁻⁴[chair] + [chair]) *100%
0.013%
The statement about the conformers is that the chair conformer is more stable, and because of that is more present. So, the answer agrees with it.