Answer:
The molar amount of gas.
Explanation:
According to the ideal gas law,
PV = nRT
P = pressure of gas
V = volume of gas
n = number of moles of gas
R = ideal gas constant
T= temperature of gas
When pressure, volume and temperature of gas is known the molar amount of gas can be determine by using above formula.
For example:
P = 1.2 atm
R = 0.0821 atm. L.mol⁻¹ .k⁻¹
T = 293 K
V = 2 L
n = ?
Solution:
PV = nRT
1.2 atm × 2L= n × 0.0821 atm. L.mol⁻¹ .k⁻¹ × 293 K
n = 1.2 atm × 2L / 0.0821 atm. L.mol⁻¹ .k⁻¹ × 293 K
n = 0.1 mol
Answer:
Part a: The IR spectrum is not sufficient due to the similar radical group presence in both product and reactants.
Part b: Mass Spectrum data is required in addition to the IR data for confirming the presence of recrystallized product.
Part c: The additional data is consistent with the expectations as the data is in support of that.
Explanation:
Part a
Acetanilide has a characteristic IR peak at around 3100-3200 cm^-1 (N-H Stretching) and 1500-1680 cm^-1 (C=O Stretching). Since a similar radical group (
) is present in the 4-bromoacetanilide, thus it is difficult to affirm the presence of the product solely on the basis of IR spectrum.
Part b
Mass Spectral data will affirm the presence of recrystallized product with certainty.
Part c
4-bromoacetanilide will have
peak at two points (213 & 215) corresponding to the two Bromine isotopes (79 & 81).
Also parent peak at 171 (
=43) will be in 49:51 due to presence of Bromine atoms.
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