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zubka84 [21]
3 years ago
6

At STP there is 112L of HCl gas in a container. Read the stem and answer Q. No. 1 & 2.

Chemistry
1 answer:
KIM [24]3 years ago
4 0

You have four fixed-volume containers at STP. Container A has 0.5 mol of gas in 11.2L. Container B has 2 mol of gas in 22.4 L. Container C has 1 mol of gas in 22.4L. Container D has 2 Mol gas of gas in 11.2 L. Which of the four containers have equal pressures

A and C

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M = 163 m/z) is formed.
DanielleElmas [232]

Answer:

            As the molecular mass of given amine is 163 g/mol (a odd number) it means that this compound contains a odd number of Nitrogen atoms. We will first apply Rule of Thirteen to get the molecular formula.

Rule of Thirteen:

First divide the parent peak value by 13 as,

                = 163 ÷ 13

                = 12.53

Now, multiply 13 by 12,

                = 13 × 12 (here, 12 specifies number of carbon atoms)

                = 156

Now subtract 156 from 163,

                = 163 - 156

                = 7

Add 7 into 12,

                = 7 + 12

                = 19 (hydrogen atoms)

So, the rough formula we have is,

                                                       C₁₂H₁₉

Now, add one Nitrogen atom to above formula and subtract one Carbon and 2 Hydrogen atoms as these numbers are equal to atomic mass of Nitrogen atom as,

                C₁₂H₁₉   -------N-------->    C₁₁H₁₇N

Also, as shown in ¹³C-NMR there is one peak around 180 ppm and the peak at 1661 cm⁻¹ in IR spectrum is characteristic to carbonyl group hence, we will add one oxygen atom to the chemical formula accordingly. i.e.

                C₁₁H₁₇N   -------O-------->    C₁₀H₁₃NO

Molecular Formula: C₁₀H₁₃NO

Also,

In NMR the the four peaks around 120 ppm are assigned to a mono substituted benzene ring.

The absence of IR peak above 3200 cm⁻³ also confirms that the amine is tertiary in nature and there is no hydrogen attached to the nitrogen atom.

It can be observed that the peaks in upfield are duplicating. This can be due to the presence of rotamers of said compound.

The most plausible structure for given data is shown below, and the resonance structure along with rotamers are also shown.

6 0
3 years ago
In the reaction, A → Products, the rate constant is 3.6 × 10−4 s−1. If the initial concentration of A is 0.548 M, what will be t
Arada [10]

Answer:

        \large\boxed{\large\boxed{0.529M}}

Explanation:

Since the <em>rate constant</em> has units of <em>s⁻¹</em>, you can tell that the order of the reaction is 1.

Hence, the rate law is:

       r=d[A]/dt=-k[A]

Solving that differential equation yields to the well known equation for the rates of a first order chemical reaction:

      [A]=[A]_0e^{-kt}

You know [A]₀, k, and t, thus you can calculate [A].

       [A]=0.548M\times e^{-3.6\cdot 10^{-4}/s\times99.2s}

       [A]=0.529M

7 0
3 years ago
The number of neutrons in an atom can be found by subtracting the atomic number from the what?
Svetradugi [14.3K]

Answer:

This approximation of mass can be used to easily calculate how many neutrons an element has by simply subtracting the number of protons from the mass number. Protons and neutrons both weigh about one atomic mass unit or amu. Isotopes of the same element will have the same atomic number but different mass numbers.

Explanation:

3 0
3 years ago
Read 2 more answers
27 Which energy conversion must occur in an operating electrolytic cell?
Vitek1552 [10]
<u> electrical energy to chemical energy</u>
5 0
3 years ago
The pressure of a gas contained in a cylinder with a movable
insens350 [35]

Answer:

B) 244.5

Explanation:

2.62 torr =349.3046 pascals.

349.3046*0.7 sq meter = 244.5 N

4 0
3 years ago
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