Answer : The redox reactions are:
Explanation :
Redox reaction or Oxidation-reduction reaction : It is defined as the reaction in which the oxidation and reduction reaction takes place simultaneously.
Oxidation reaction : It is defined as the reaction in which a substance looses its electrons. In this, oxidation state of an element increases. Or we can say that in oxidation, the loss of electrons takes place.
Reduction reaction : It is defined as the reaction in which a substance gains electrons. In this, oxidation state of an element decreases. Or we can say that in reduction, the gain of electrons takes place.
(1)
This reaction is a redox reaction.
In this reaction, the oxidation state of 'Ca' changes from (0) to (+2) that means 'Ca' lost 2 electrons and it shows oxidation reaction and the oxidation state of 'Cl' changes from (0) to (-1) that means 'Cl' gain 1 electron and it shows reduction reaction.
(2)
This reaction is a double-displacement reaction in which the cation of two reactants molecule exchange their places to give two different products.
In double-displacement reaction, the oxidation state of cation and anion remains same on both side of the reaction. So, it is not a redox reaction.
(3)
This reaction is a redox reaction.
In this reaction, the oxidation state of 'Zn' changes from (0) to (+2) that means 'Zn' lost 2 electrons and it shows oxidation reaction and the oxidation state of 'Fe' changes from (+2) to (0) that means 'Fe' gain 2 electron and it shows reduction reaction.
(4)
This reaction is a double-displacement reaction in which the cation of two reactants molecule exchange their places to give two different products.
In double-displacement reaction, the oxidation state of cation and anion remains same on both side of the reaction. So, it is not a redox reaction.