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grigory [225]
3 years ago
15

Calculate the concentrations of all species present in a 0.26 M solution of ethylammonium chloride (C2H5NH3Cl).

Chemistry
1 answer:
Alina [70]3 years ago
5 0

Answer:

0.00000223

Explanation:

pKa for C2H5NH3+ = 10.7

pKw = 14.0

pKa + pKb = pKw

10.7 + pKb = 14.0

pKb = 14.0 - 10.7

pKb = 3.30

C2H5NH3Cl is a salt of ethylamine and HCl so it will dissolve in water to produce  C2H5NH3^+ + Cl^-

The base hydrolysis reaction:  C2H5NH3^+(aq) + H2O(l) <=> C2H5NH2(aq) + H3O^+(aq)

This reaction is described by Kb.

Kb = [C2H5NH2][H3O^+]/[C2H5NH3^+]

Let [C2H5NH2] = [H3O^+] = x,

so [C2H5NH3^+] = 0.26 - x

Kb = x^2/(0.26 - x) = 2.00 x 10^-11  

Let's solve for x. In this equation,  It is possible to solve without the use quadratic equation. So we can assume that 0.26 - x  is approximately equal to 0.26.  We won't know until we do the calculation.

We get:  x^2 + 2.00 x 10^-11x - 4.99 x 10^-12 = 0

With the use of a quadratic calculator.

x = 2.23 x 10^-6 M = [C2H5NH2] = [H3O^+]

0.26 - x  is just 0.26 M in this problem because 2.23 x 10^-6 M is insignificant.

[C2H5NH3^+] = 0.26 M = [Cl^-]

NOTE:

pH = -log [H3O^+] = -log(2.23 x 10^-6) = 5.65

Ka is the acid dissociation constant

Kb is the base dissociation constant

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guys please help me WILL MARK BARINLIEST If you have 5.7 x 10^24 molecules of O2 at STP, how many liters of O2 do you have? must
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Answer:

212.8 dm^3 or L

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5 0
2 years ago
The atomic masses of 151eu and 153eu are 150.919860 and 152.921243 amu, respectively. The average atomic mass of europium is 151
vitfil [10]

Answer:-  The natural abundance of ^1^5^1_E_u is 0.478 or 47.8% and ^1^5^3_E_u is 0.522 or 52.2% .

Solution:- Average atomic mass of an element is calculated from the atomic masses of it's isotopes and their abundances using the formula:

Average atomic mass = mass of first isotope(abundance) + mass of second isotope(abundance)

We have been given with atomic masses for ^1^5^1_E_u and ^1^5^3_E_u as 150.919860 and 152.921243 amu, respectively.  Average atomic mass of Eu is 151.964 amu.

Sum of natural abundances of isotopes of an element is always 1. If we assume the abundance of ^1^5^1_E_u as n then the abundance of ^1^5^3_E_u would be 1-n .

Let's plug in the values in the formula:

151.964=150.919860(n)+152.921243(1-n)

151.964=150.919860n+152.921243-152.921243n

on keeping similar terms on same side:

151.964-152.921243=150.919860n-152.921243n

-0.957243=-2.001383n

negative sign is on both sides so it is canceled:

0.957243=2.001383n

n=\frac{0.957243}{2.001383}

n=0.478

The abundance of ^1^5^1_E_u is 0.478 which is 47.8%.  

The abundance of ^1^5^3_E_u is = 1-0.478

= 0.522 which is 52.2%

Hence, the natural abundance of ^1^5^1_E_u is 0.478 or 47.8% and ^1^5^3_E_u is 0.522 or 52.2% .


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