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Zielflug [23.3K]
3 years ago
14

When a stable diatomic molecule spontaneously forms from its atoms, what are the signs of Delta H, Delta S, and Delta G? A. + +

+ B. + - - C. - - + D. - - -
Chemistry
1 answer:
Neko [114]3 years ago
3 0
H will definitely be positive because a bond is always more stable than no bond surely if it is a sigma bond.
For G you can't really know because you don't know how much energy is provided by the bond and if it outways the loss in disorder.


The reaction will become more spontaneous with a lower temperature because H tells you the reaction is exotherm
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The value of Ka for nitrous acid (HNO2) at 25 ∘C is 4.5×10−4 .a. Write the chemical equation for the equilibrium that correspond
kvv77 [185]

Answers and Explanation:

a)- The chemical equation for the corresponden equilibrium of Ka1 is:

2. HNO2(aq)⇌H+(aq)+NO−2

Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.

b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:

ΔG= ΔGº + RT ln Q

Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)

At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:

⇒ 0 = ΔGº + RT ln Ka

   ΔGº= - RT ln Ka

   ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)

  ΔGº= 19092.8 J/mol

c)- According to the previous demonstation, at equilibrium ΔG= 0.

d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:

ΔG= ΔGº + RT ln Q

Q= ((H⁺) (NO₂⁻))/(HNO₂)

Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)

Q= 1.88 10⁻⁴

We know that   ΔGº= 19092.8 J/mol, so:

ΔG= ΔGº + RT ln Q

ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)

ΔG= -2162.4 J/mol

Notice that ΔG<0, so the process is spontaneous in that direction.

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3 years ago
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If the distance between two objects is decreased to - of the original
Charra [1.4K]

Answer:

The new force will be \frac{1}{100} of the original force.

Explanation:

In the context of this problem, we're dealing with the law of gravitational attraction. The law states that the gravitational force between two object is directly proportional to the product of their masses and inversely proportional to the square of a distance between them.

That said, let's say that our equation for the initial force is:

F = G\frac{m_1m_2}{R^2}The problem states  that  the distance decrease to 1/10 of the original distance, this means:[tex]R_2 = \frac{1}{10}R

And the force at this distance would be written in terms of the same equation:

F_2 = G\frac{m_1m_2}{R_2^2}

Find the ratio between the final and the initial force:

\frac{F_2}{F} = \frac{G\frac{m_1m_2}{R_2^2}}{G\frac{m_1m_2}{R^2}}

Substitute the value for the final distance in terms of the initial distance:

\frac{F_2}{F} = \frac{G\frac{m_1m_2}{(\frac{R}{10})^2}}{G\frac{m_1m_2}{R^2}}

Simplify:

\frac{F_2}{F} = \frac{\frac{1}{100R^2}}{\frac{1}{R^2}}=\frac{1}{100}

This means the new force will be \frac{1}{100} of the original force.

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