For each of the following questions give the name of an element from period 2 lithium to neon which matches the description elem
1 answer:
You might be interested in
Sodium-22 remain : 1.13 g
<h3>Further explanation </h3>The atomic nucleus can experience decay into 2 particles or more due to the instability of its atomic nucleus.
Usually, radioactive elements have an unstable atomic nucleus.
General formulas used in decay:
T = duration of decay
t 1/2 = half-life
N₀ = the number of initial radioactive atoms
Nt = the number of radioactive atoms left after decaying during T time
half-life = t 1/2=2.6 years
T=15.6 years
No=72.5 g
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.