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To solve for the number of moles, we simply have to use the Avogadros number which states that there are 6.022 x 10^23 molecules per mole. Therefore:
number of moles = 6.67 X 10^40 chlorine molecules / (6.022 x 10^23 molecules / mole)
number of moles = 1.108 x 10^17 moles
<u>Answer:</u> The volume of barium chlorate is 195.65 mL
<u>Explanation:</u>
To calculate the volume of solution, we use the equation used to calculate the molarity of solution:

Given mass of barium chlorate = 25.0 g
Molar mass of barium chlorate = 304.23 g/mol
Molarity of solution = 0.420 mol/L
Volume of solution = ?
Putting values in above equation, we get:

Hence, the volume of barium chlorate is 195.65 mL