The total pressure of a mixture of hydrogen, oxygen, and methane is 96.4 kPa. The partial pressures of hydrogen and oxygen are 1
1 answer:
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Answer:
a) [Tris0] : [Tris] = 1 : 100
b) Range = 7.1 to 9.1
Explanation:
a) Calculation of ratio of the basic and the acidic forms of tris
pH of a buffer is calculate using Henderson-Hasselbalch equation
Conjugate acid of Tris dissociated as
For tris,
Salt or Basic form = tris0
Acid or Acidic form = Tris
pKa = 8.1
pH = 6.1
[Tris0] : [Tris] = 1 : 100
b) Range of Tris
Range of any buffer is:
From (pKa -1) to (pKa+1)
So, range of Tris is:
From (8.1 - 1) to (8.1 +1)
or from 7.1 to 9.1
Answer:
See explanation below
Explanation:
In this reaction we have the ethyl acetoacetate which is reacting with 2 eq of sodium etoxide. The sodium etoxide is a base and it usually behaves as a nucleophyle of many reactions. Therefore, it will atract all the acidics protons in a molecule.
In the case of the ethyl acetoacetate, the protons that are in the methylene group (CH3 - CO - CH2 - COOCH2CH3) are the more acidic protons, therefore the etoxide will substract these protons instead of the protons of the methyl groups. This is because those hydrogens (in the methylene group) are between two carbonile groups, which make them more available and acidic for any reaction. As we have 2 equivalents of etoxide, means that it will substract both of the hydrogen atoms there, and then, reacts with the Br - CH2CH2 - Br and form a product of an aldolic condensation.
The mechanism of this reaction to reach X is shown in the attached picture.
