According to Henderson–Hasselbalch Equation,
pH = pKa + log [Acetate] / [Acetic Acid]
As,
pKa = -log Ka
pKa = -log (1.8 × 10⁻⁵)
pKa = 4.74
So,
pH = 4.74 + log [Acetate] / [Acetic Acid]
4.34 = 4.74 + log [Acetate] / [Acetic Acid]
4.34 - 4.74 = log [Acetate] / [Acetic Acid]
-0.40 = log [Acetate] / [Acetic Acid]
Taking Antilog on both sides,
[Acetate] / [Acetic Acid] = 0.398
In secondary structure of a protein, other than peptide bonds, hydrogen bond are formed.
The secondary structure contains regions of amino acid chains that are stabilized by hydrogen bonds from the polypeptide backbone. arrangement of hydrogen bonds between the peptide it is an arrangement nitrogen's and the peptide carbonyl oxygens of different amino acid residues. the most common types of secondary structures are the α helix and the β pleated sheet. both structures are held in shape by hydrogen bonds, which form between the carbonyl O of one amino acid and the amino H of another.
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The volume decreases in the same ratio as the ratio of pressure increases
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