Answer:
The pH value of the mixture will be 7.00
Explanation:
Mono and disodium hydrogen phosphate mixture act as a buffer to maintain pH value around 7. Henderson–Hasselbalch equation is used to determine the pH value of a buffer mixture, which is mathematically expressed as,
![pH=pK_{a} + log(\frac{[Base]}{[Acid]})](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%20%2B%20log%28%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%29)
According to the given conditions, the equation will become as follow
![pH=pK_{a} + log(\frac{[Na_{2}HPO_{4} ]}{[NaH_{2}PO_{4}]})](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%20%2B%20log%28%5Cfrac%7B%5BNa_%7B2%7DHPO_%7B4%7D%20%5D%7D%7B%5BNaH_%7B2%7DPO_%7B4%7D%5D%7D%29)
The base and acid are assigned by observing the pKa values of both the compounds; smaller value means more acidic. NaH₂PO₄ has a pKa value of 6.86, while Na₂HPO₄ has a pKa value of 12.32 (not given, but it's a constant). Another more easy way is to the count the acidic hydrogen in the molecular formula; the compound with more acidic hydrogens will be assigned acidic and vice versa.
Placing all the given data we obtain,
<u>Answer:</u> The standard free energy change of formation of 
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:
Relation between standard Gibbs free energy and equilibrium constant follows:
where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:
For the given chemical equation:
The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of is 92.094 kJ/mol
Answer:
Element: H (hydrogen)
Compound: H2O (water)
Explanation: An element is made up of a singular atom while a compound is made up of 2 or more
Na₂CO₃ is a stronger base while
Na₂CO₃ puts more OH- ion into solution
The strongest base is [H₊]= 10 - 12
The strongest acid is PH = 0.5
If an acid is added to neutral water the H₊
will increase but when an acid added to neutral water
the OH⁻ will decrease.
