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Dennis_Churaev [7]

3 years ago

6

At what temperature would a gas have a volume of 13.5 L at a pressure of 0.723 atm, if it had a volume of 17.8 L at a pressure o

f 0.612 atm and a temperature of 28 C

1 answer:

MA_775_DIABLO [31]3 years ago

5 0

Answer : The initial temperature of gas would be, 269.7 K

Explanation :

Combined gas law is the combination of Boyle's law, Charles's law and Gay-Lussac's law.

The combined gas equation is,

$\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}$

where,

$P_1$ = initial pressure of gas = 0.723 atm

$P_2$ = final pressure of gas = 0.612 atm

$V_1$ = initial volume of gas = 13.5 L

$V_2$ = final volume of gas = 17.8 L

$T_1$ = initial temperature of gas = ?

$T_2$ = final temperature of gas = $28^oC=273+28=301K$

Now put all the given values in the above equation, we get:

$\frac{0.723atm\times 13.5L}{T_1}=\frac{0.612atm\times 17.8L}{301K}$

$T_1=269.7K$

Thus, the initial temperature of gas would be, 269.7 K

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Predict whether aqueous solutions of the following substances are acidic, basic, or neutral:

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Answer:

A. Acidic

B. Neutral

C. Basic

D. Acidic

E. Basic

Explanation:

The reaction of salts with water to give aqueous solutions which are either acidic, basic or neutral is known as salt hydrolysis. Salts that are produced from the reaction of strong acids and weak bases give acidic solutions. Salts that are produced the reaction between weak acids and strong bases give basic solutions. Neutral solutions are obtained from salts produced bynthe reaction of strong acids and strong bases.

The hydrolysis of the given salts are shown below:

A. AlCl₃ + 3 H₂O ---> 3 HCl + Al(OH)₃

The aqueous solution produced will be acidic since HCl is a strong acid while Al(OH)₃ is a weak base.

B. NaBr + H₂O ----> HBr + NaOH

The aqueous solution produced will be neutral since HBr is a strong acid and NaOH is strong base as well.

C. NaClO + H₂O ----> HClO + NaOH

The aqueous solution produced will be basic since HClO is a weak acid while NaOH is a strong base.

D. CH₃NH₃NO₃ + H₂O ----> HNO₃ + CH₃NH₂ + H₂O

The aqueous solution produced will be acidic since HNO₃ is a strong acid while CH₃NH₂ is a weak base.

E. Na₂SO₃ + 2 H₂O ----> H₂SO₃ + 2 NaOH

The aqueous solution produced will be basic since H₂SO₃ is a weak acid while NaOH is a strong base.

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For the following reactions, predict the products and write the balanced formula equation, complete ionic equation, and net ioni

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Answer:

.

Explanation:

To predict the products of these reactions we need to know the kind of reactions. All these reactions are double replacement reaction. In these kinds of reactions, the products will be the result of exchanging ions in the reactants. So, the first step is to identify the ions.

For the reaction, we have Hg2(NO3)2 and CuSO4. We have the ions Hg+1, NO3-1, Cu+2 and SO4-2

The way to make this exchange is putting together positive in one species with the negative of the other species. Following that rule we have

$Hg^{+1} - - - (SO_{4})^{-2}[/text]
the oxidation number will tell you the subscript for each species in the compound. In this case, is Hg2(SO4) [tex]Cu^{+2} - - - (NO_{3})^{-1} - - -> Cu(NO_{3})_{2} [/text] 
So, the products for this reaction will be
 [tex]Hg_{2} (NO_{3})_{2}(aq) + CuSO_{4}(aq) --> Hg_{2}SO_{4} + Cu(NO_{3})_{2}[/text]

After this, we proceed to balance the equation. For this, we check that we have the same number of each element on both sides of the equation. In this case, we can see that we have the same number, so the equation is balanced. Finally, we check the rules of solubility to see if the species are soluble in water or not. In this case sulfates area always soluble except for mercury so Hg2(SO4) precipitates in the solution (pre). Nitrates are always soluble so Cu(NO3)2 is soluble (aq) 
[tex] Hg_{2}(NO_{3})_{2}(aq) + CuSO_{4}(aq) - -> Hg_{2}SO_{4} (pre) + Cu(NO_{3})_{2}(aq)$

The complete ionic equation allows to show which of the reactants or products exist primarily as ions. For this reaction this will be:

$2Hg^{+1}(aq) + 2(NO_{3})^{-1}(aq) + (SO_{4})^{-2}(aq) + Cu^{+2}(aq) --> Hg_{2}SO_{4} (pre)+ Cu^{+2}(aq) + (NO_{3})^{-1}(aq) [/text]

To get net ionic equation we take away the ions that did not participate in the reactions. In other words the ones that are the same on both sides in the equation. In this case we see that [tex] Cu^{+2}(aq) and (NO_{3})^{-1}(aq) [/text] are the same on both sides so those ions are not include in the net ionic equation. This is:
[tex] 2Hg^{+1}(aq) + (SO_{4})^{-2}(aq) --> Hg_{2}SO_{4} (pre) [/text]

B [tex] Ni(NO_{3})_{2}(aq) + CaCl_{2}(aq)$

ions (1) $Ni^{+2} and (NO_{3})^{-1}$

ions (2) $Ca^{+2} and Cl^{-1}$

Exchanging

$Ni^{+2} ---- Cl^{-1} --> NiCl_{2}$

$Ca^{+2} --- (NO_{3})^{-1} --> Ca(NO_{3})_{2}$

Products

$Ni(NO_{3})_{2}(aq) + CaCl_{2}(aq) --> NiCl_{2} + Ca(NO_{3})_{2}$

The equation is already balanced

Chlorides are always soluble except Ag+, TI+, Pb+2 and Hg2+2. NiCl2 is soluble (aq)

Nitrates are always soluble. Ca(NO3)2 is soluble (aq)

Since both compounds are soluble, we can say that there is not reaction.

Complete ionic equation

$Ni^{+2}(aq) + 2(NO_{3})^{-1} (aq) + Ca^{+2}(aq) + 2Cl^{-1}(aq) - - > Ni^{+2}(aq) + 2(NO_{3})^{-1} (aq) + Ca^{+2}(aq) + 2Cl^{-1}(aq)$

Net ionic equation:

The ions in both sides of the equation are the same so all of them are cancelled and we cannot get a net ionic equation this explains why there is no reaction in this case.

C $K_{2}CO_{3}(aq) + MgI_{2}(aq)$

Ions(1) $K^{+1} and (CO_{3})^{-2}$

Ions(2) $Mg^{+2} and l^{-1}$

Exchanging

$K^{+1} --- l^{-1} - - > KI$

$Mg^{+2} --- (CO_{3})^{-2} - - > Ca(CO_{3})$

Products

$K_{2}CO_{3}(aq) + MgI_{2}(aq) - -> Kl + MgCO_{3}$

The equation is not balanced

Balance equation is

$K_{2}CO_{3}(aq) + MgI_{2}(aq) - -> 2Kl (aq) + MgCO_{3} (pre)$

iodides are always soluble except Ag+, TI+, Pb+2 and Hg2+2. KI is soluble (aq)

carbonates are always insoluble except group 1 cations. MgCO3 is insoluble (pre)

complete ionic equation

$2K^{+1}(aq) + (CO_{3})^{-2}(aq) + Mg^{+2}(aq) + 2l^{-1}(aq) - - > MgCO_{3} (pre) + 2K^{+1}(aq) + 2l^{-1}(aq)$

Net ionic equation

$(CO_{3})^{-2}(aq) + Mg^{+2}(aq) - - > MgCO_{3} (pre)$

D $Na_{2}CrO_{4}(aq) + AlBr_{3}(aq)$

Ions(1) $Na^{+1} and (CrO_{4})^{-2}$

Ions(2) $Al^{+3} and Br^{-1}$

Exchanging

$Na^{+1} ---- Br^{-1} - -> NaBr$

$Al^{+3} --- (CrO_{4})^{-2} - -> Al_{2}(CrO_{4})_{3}$

Products

$Na_{2}CrO_{4}(aq) + AlBr_{3}(aq) - -> NaBr + Al_{2}(CrO_{4})_{3}$

The equation is not balanced

Balance equation is

$3Na_{2}CrO_{4}(aq) + 2AlBr_{3}(aq) - -> 6NaBr + Al_{2}(CrO_{4})_{3}$

bromides are always soluble except Ag+, TI+, Pb+2 and Hg2+2. NaBr is soluble (aq)

chromates are always insoluble except group 1 cations. Al2(CrO4)3 is insoluble (pre)

$3Na_{2}CrO_{4}(aq) + 2AlBr_{3}(aq) - -> 6NaBr(aq) + Al_{2}(CrO_{4})_{3}(pre)$

Complete ionic equation

$6Na^{+1}(aq) + 3(CrO_{4})^{-2}(aq) + 2Al^{+3}(aq) + 6Br^{-1}(aq) - -> Al_{2}(CrO_{4})_{3}(pre) +6Br^{-1}(aq) + 6Na^{+1}(aq)$

Net ionic equation

$3(CrO_{4})^{-2}(aq) + 2Al^{+3}(aq) - -> Al_{2}(CrO_{4})_{3}(pre)$

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