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mrs_skeptik [129]
2 years ago
5

The isomerization of methyl isonitrile, CH3NC, to acetonitrile, CH3CN, was studied in the gas phase at 215oC, and the following

data were obtained: Time (s) [CH3NC] (M) 0 0.0165 2,000 0.0110 5,000 0.00591 8,000 0.00314 12,000 0.00137 15,000 0.00074 (a) Calculate the average rate of reaction, in M/s, for the time interval between each measurement.
Chemistry
1 answer:
Viefleur [7K]2 years ago
3 0

Answer:

2.75 × 10⁻⁶ M/s

1.69 × 10⁻⁶ M/s

9.23 × 10⁻⁻⁷ M/s

4.43 × 10⁻⁻⁷ M/s

2.1 × 10⁻⁻⁷ M/s

Explanation:

We have the following information for the isomerization of methyl isonitrile

Time (s)      [CH₃NC] (M)

  0              0.0165

2000          0.0110

5000          0.00591

8000          0.00314

12000         0.00137

15000         0.00074

To calculate the average rate of reaction (r) for each interval, we need to use the following expression:

r = -Δ[CH₃NC]/Δt

Interval 0-2000 s

r = - (0.0110 M-0.0165 M)/2000 s - 0 s = 2.75 × 10⁻⁶ M/s

Interval 2000-5000 s

r = - (0.00591 M-0.0110 M)/5000 s - 2000 s = 1.69 × 10⁻⁶ M/s

Interval 5000-8000 s

r = - (0.00314 M-0.00591 M)/8000 s - 5000 s = 9.23 × 10⁻⁻⁷ M/s

Interval 8000-12000 s

r = - (0.00137 M - 0.00314 M)/12000 s - 8000 s = 4.43 × 10⁻⁻⁷ M/s

Interval 12000-15000 s

r = - (0.00074 M - 0.00137 M)/15000 s - 12000 s = 2.1 × 10⁻⁻⁷ M/s

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Answer:

i) pH = 2

pH = -log(H+)

:- (H+) = 10^(-2)

:- (H+) = 0.01 M

ii) pH = 6

pH = -log(H+)

:- (H+) = 10^(-6)

:- (H+) = 0.000001 M

Explanation:

By definition: pH = -log(H+).

Given your pH, solve for the H+ using the the following log rule:

if a = (+/-) log (b) then

b = 10^((+/-) a).

Also remember unit of concentration is molar (M)

3 0
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How many Mol are in 4.000 grams of MgCl2 ?
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Answer:

The number of mol is: 0, 042 mol in 4 grams of MgCl2

Explanation:

We calculate the weight of 1 mol of MgCl2:

Weight 1mol of MgCl2= weight Mg + (weight Cl)x  2=

24, 3 grams + 2 x 35, 5 grams = 95, 3 grams/mol MgCl2

95, 3 grams------1 mol MgCl2

4 grams      -------x = (4 grams x1 mol MgCl2)/ 95, 3 grams= 0, 04197 mol MgCl2

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3 years ago
Explain why mixing of red paint with white paint does not constitute a chemical reaction even though the product has a different
MArishka [77]

Answer:

Explanation:

In a chemical change through chemical reactions, a new kind of matter forms. When a paint is mixed together, a physical change has occurred and not a chemical change. The different color one perceives is just a mere overlap between the reflected white and red color which produces another hue.

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5 0
3 years ago
enzyme‑catalyzed, single‑substrate reaction E + S − ⇀ ↽ − ES ⟶ E + P . The model can be more readily understood when comparing t
laila [671]

Complete Question

The complete question is shown on the first uploaded image

Answer:

[S]<<KM             |   [S]=KM                  |  [S]>>KM                     | Not true

____________  |   Half of the active  | Reaction rate is         | Increasing

[E_{free}] is about   |    sites are filled of  |    independent of      |  [E_{Total}] will                                            

 equal to [E_{total}]. |                                 |   [S]                             | lower KM

_____________________________________________|____________

[ES] is much       |                                 | Almost all active

 lower than         |                                 | sites are filled

[E_{free}]                  |                                 |

Explanation:

Generally the combined enzyme[ES] is mathematically represented as

                   [ES] = \frac{[E_{total}][S]}{K_M + [S]}----(1)

for Michaelis-Menten equation

Where [S] is the substrate concentration and K_M is the Michaelis constant

Considering the statement [S] < < K_M

  Looking at the equation [S] is denominator so it can be ignored(it is far too small compared to K_M)  hence the above equation becomes

               [ES] = \frac{[E_{total}][S]}{K_M}

Since [S] is less than K_M it means that \frac{[S]}{K_M}  < < 1

so it means that [ES] < < [E_{total}]

  What this means is that the  number of combined enzymes[ES] i.e the number of occupied site is very small compared to the the total sites [E_{total}]  i.e the total enzymes concentration which means that the free sites [E_{free}]  i.e the concentration of free enzymes is almost equal to [E_{total}]

Considering the second statement

      [S] = K_M

So  this means that equation one would now become

           [ES] = \frac{[E_{total}][S]}{2[S]} = \frac{[E_{total}]}{2}

So this means that half of the active sites that is the total enzyme concentration are filled with S

Considering the Third Statement

      [S] >>K_M

In this case the K_M in the denominator of equation 1 would be neglected and the equation becomes

       [ES] = \frac{[E_{total}] [S]}{[S]} = [E_{total}]

This means that almost all the sites are occupied with substrate

 The rate of this reaction is mathematically defined as

             v =\frac{V_{max}[S]}{K_M [S]}

Where v is the rate of the reaction(also know as the velocity of the reaction at a given time t) and V_{max}  is he maximum velocity of the reaction

In this case also the K_M at the denominator would be neglected as a result of the statement hence the equation becomes

                v = \frac{V_{max}[S]}{[S]} = V_{max}

So it means that the reaction does not depend on the concentration of substrate [S]

For the final statement(Not True ) it would match with condition that states that increasing [E_{total}] will lower K_M

This is because K_M does not depend on enzyme concentration it is a property of a enzyme

             

       

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To what extent do covalent compounds conduct electricity?
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The answer is never because there's no electricity

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