Answer:- Mole ratio of D to A is 4:3.
Explanations:- Mole ratio for a chemical reaction is the ratio of the coefficients.
The given generic chemical reaction is:

The numbers written in front of each chemical species in the chemical reaction are their moles. For the given generic chemical reaction the coefficient of A is 3 and that of B is 1. So, the mole ratio of A to B is 3:1.
Similarly if we want to write the mole ratio of C to D then it is 1:4.
We are asked to write the mole ratio of D to A. So, like the other ratios, the mole ratio of D to A is 4:3 as the coefficient of D is 4 and A is 3.
C. a burning candle
all the other choices are physical changes
Among the elements Barium has the lowest Ionization Energy.
<h3>What is Ionization Process ?</h3>
The process by which any neutral atom gets converted into electrically charged by gaining or losing electron is called Ionization Process.
K is an alkali metal it has to lose one electron to attain stable electronic configuration of an inert gas
For removing second electron , a stable configuration has to be broken and so will require high amount of energy.
Ca and Ba are alkaline earth metals.
They both have to lose 2 electrons to attain stable electronic configuration of noble gas.
They have low Iow Ionization Energy as compared to K.
Ca has higher Ionization Energy as compared to Ba because when we move down the periodic table , The ionization energy decreases.
Hence , Among the elements Barium has the lowest Ionization Energy.
To know more about Ionization Process
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After a good long amount of research, I found that the scientific answer to this question would be a big ol’ dink