We can assume that every mole of ethanol needs 2 moles of Dichromate to react.
So if in 1L we have 0.05961 moles of dichromate we can discover how many moles we have in 35.46mL
1000 mL - 0.05962 moles
35.46 mL - x
x =
x = 2,11* 10^-3 moles
As we said earlier, 1 mole of ethanol needs 2 mole of dichromate, so in the solution we have 1,055*10^-3 moles of ethanol. We can discover the mass of ethanol present in the solution.
1 mole - 46g
1.055*10^-3 - y
y = 46 * 1.055*10^-3
y = 0.048 g
To discover the percent of alchol we can use a simple relation