Option C coz it should be ( CNH4)2. Hope i cleared your doubt
Answer:
B) All carbon atoms have 6 neutrons.
Explanation:
The false statement from the given choices is that all carbon atoms have 6 neutrons.
There is a phenomenon called isotopy in chemistry.
Isotopy is the existence of two or more atoms of the same element having the same atomic number but different mass numbers due to the differences in the number of neutrons in their various nuclei.
- These atoms of elements are called isotopes.
- Carbon atoms generally have proton number of 6 which is the same as the atomic number.
- As with all atoms, the mass number or atomic mass equals the number of protons and neutrons.
For the isotopes of carbon, their number of neutrons differs.
For example:
<em>¹²₆C ¹³₆C ¹⁴₆C</em>
The number of neutrons differs in the above isotopes.
Number of neutrons = mass number - atomic number;
¹²₆C , number of neutrons = 12 - 6 = 6
¹³₆C, number of neutrons = 13 - 6 = 7
¹⁴₆C, number of neutrons = 14 - 6 = 8
Therefore, based on the concept of isotopy, all carbon atoms do not have 6 neutrons.
According to Raoult's low:
We will use this formula: Vp(Solution) = mole fraction of solvent * Vp(solvent)
∴ mole fraction of solvent = Vp(Solu) / Vp (Solv)
when we have Vp(solu) = 25.7 torr & Vp(solv) = 31.8 torr
So by substitution:
∴ mole fraction of solvent = 25.7 / 31.8 =0.808
when we assume the moles of solute NaCl = X
and according to the mole fraction of solvent formula:
mole fraction of solvent = moles of solvent / (moles of solvent + moles of solute)
by substitute:
∴ 0.808 = 0.115 / (0.115 + X)
So X (the no.of moles of NaCl) = 0.027 m
Hydrogen sulfide gas is reacted with dioxygen gas to produce gaseous sulfur dioxide and water. It is false.
When hydrogen sulfide gas reacts with dioxygen gas, it produces water and solid Sulphur and not gaseous sulfur. The chemical equation of the given substances is :
2H2S + O2 → 2S + 2H20
It is a redox reaction as both Oxidation and reduction happens in it. Oxidation of hydrogen sulphur to sulphur happens and reductions of oxygen to water takes place.
if you need to learn more about chemical reaction of Hydrogen sulfide gas, click here
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To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:
I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
Cl
=
3.5
Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
143 pm
r
C
−
F
≈
135 pm
r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
So assuming the answer is truly
C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
The now more electropositive carbon wishes to attract bonding pairs from chlorine closer, thereby shortening the
C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
