Answer:
The boiling point is 308.27 K (35.27°C)
Explanation:
The chemical reaction for the boiling of titanium tetrachloride is shown below:
Ti
⇒ Ti
ΔH°
(Ti) = -804.2 kJ/mol
ΔH° (Ti) = -763.2 kJ/mol
Therefore,
ΔH° = ΔH° (Ti) - ΔH° (Ti) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol
Similarly,
s°(Ti) = 221.9 J/(mol*K)
s°(Ti) = 354.9 J/(mol*K)
Therefore,
s° = s° (Ti) - s°(Ti) = 354.9 - 221.9 = 133 J/(mol*K)
Thus, T = ΔH° /s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C
Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.
The shape of a molecule is determined by the location of the nuclei and its electrons. ... Molecular geometry, on the other hand, depends on not only on the number of electron groups, but also on the number of lone pairs. When the electron groups are all bond pairs, they are named exactly like the electron-group geometry.
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