The gas is in a rigid container: this means that its volume remains constant. Therefore, we can use Gay-Lussac law, which states that for a gas at constant volume, the pressure is directly proportional to the temperature. The law can be written as follows:

Where P1=5 atm is the initial pressure, T1=254.5 K is the initial temperature, P2 is the new pressure and T2=101.8 K is the new temperature. Re-arranging the equation and using the data of the problem, we can find P2:

So, the new pressure is 2 atm.
From what I can see it's D, I did this by simply examining the other answers and seeing that they are beneficial, so, from that information, this one must not be.
Explanation:
Given that,
Wavelength = 6.0 nm
de Broglie wavelength = 6.0 nm
(a). We need to calculate the energy of photon
Using formula of energy



(b). We need to calculate the kinetic energy of an electron
Using formula of kinetic energy


Put the value into the formula


(c). We need to calculate the energy of photon
Using formula of energy



(d). We need to calculate the kinetic energy of an electron
Using formula of kinetic energy


Put the value into the formula


Hence, This is the required solution.
A. molecules are CONSTANTLY moving.