He structure of the product, C, of the following sequence of reactions would be:
1 answer:
Answer:
I
Explanation:
The complete question can be seen in the image attached.
We need to understand what is actually going on here. In the first step that yields product A, the sodamide in liquid ammonia attacks the alkyne and abstracts the acidic hydrogen of the alkyne. The second step is a nucleophilic attack of the C6H5C≡C^- on the alkyl halide to yield product B (C6H5C≡C-CH3CH2).
Partial reduction of B using the Lindlar catalyst leads to syn addition of hydrogen to yield structure I as the product C.
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Answer:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
Explanation:
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In this case, according to the given information, it turns out possible for us use the thermodynamic definition of the Gibbs free energy and its relationship with Ksp as follows:
Thus, by combining them, we obtain:
Which is related to the general line equation:
Whereas:
It means that we answer to the blanks as follows:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
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