Missing in your question Ka2 =6.3x10^-8
From this reaction:
H2SO3 + H2O ↔ H3O+ + HSO3-
by using the ICE table :
H2SO3 ↔ H3O + HSO3-
intial 0.6 0 0
change -X +X +X
Equ (0.6-X) X X
when Ka1 = [H3O+][HSO3-]/[H2SO3]
So by substitution:
1.5X10^-2 = (X*X) / (0.6-X) by solving this equation for X
∴ X = 0.088
∴[H2SO3] = 0.6 - 0.088 = 0.512
[HSO3-] = [H3O+] = 0.088
by using the ICE table 2:
HSO3- ↔ H3O + SO3-
initial 0.088 0.088 0
change -X +X +X
Equ (0.088-X) (0.088+X) X
Ka2= [H3O+] [SO3-] / [HSO3-]
we can assume [HSO3-] = 0.088 as the value of Ka2 is very small
6.3x10^-8 = (0.088+X)*X / 0.088
X^2 +0.088 X - 5.5x10^-9= 0 by solving this equation for X
∴X= 6.3x10^-8
∴[H3O+] = 0.088 + 6.3x10^-8
= 0.088 m ( because X is so small)
∴PH= -㏒[H3O+]
= -㏒ 0.088 = 1.06
Volume = 22.4 dm3
n = 2 mol of H2
n = 1 mol of N2
Temperature = 273.15
All H2 reacts
reaction
N2 + 3H2 = 2NH3
1:3 ratio
Calculation:
N2 initial - N2 reacted = Final N2
1 - 2*(1/3) = 0.3333 mol of N2 left
H2 = 0 left
NH3 formed = 2/3*1 = 2/3 = 0.666
Total mol:
0.3333 + 0.666 = 1 mol
Apply the equation :
PV = nRT
P = nRT/V = 1*0.0082*(273.15)/(22.4) = 0.0999924 atm
PH2 = 0
PN2 = 1/3*0.0999924 = 0.0333308 atm
PNH3 = 2/3*0.0999924 = 0.0666616 atm
Answer is 0.0666616 atm
The answer to this question would be: <span> 10 °K
Kelvin and Celcius scales are different by 273</span> degrees but their ratio is the same. One degree in Kelvin is equal to one degree in Celcius. That mean, 10 °C change in Celcius would be same as <span> 10 °K changes in Kelvin too. </span>
Generally speaking, organic molecules tend to dissolve in solvents that have similar physical properties. A good rule of thumb is that "like dissolves like". Meaning, polar compounds can dissolve polar compounds and nonpolar compounds can dissolve nonpolar compounds.
To apply this to the current problem, we are told that the brushes are being cleaned with vegetable oil or mineral oil. In this case, the oils are used as solvents. In order for these solvents to be effective, the compounds they are trying to dissolve must be similar in structure and properties to other oils. Therefore, vegetable oil or mineral oil will be most effective in removing oil-based paints, as these will have the similar properties needed to dissolve in the oil solvents.
