Answer: Because this does not dissolve in water - it forms a barrier on the surface of the unreacted CaCO3 which prevents any further reaction. A small volume of CO2 is produced , but this stops after a short time . Conclusion: H2SO4 cannot be used with CaCO3 to produce CO2 gas .
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PH of acidic buffer = pKa + log [CH₃COONa - HCl] / [CH₃COOH + HCl]
pKa of CH₃COOH = 4.74
Concentration of acetic acid in buffer = 2.0 M
Concentration of sodium acetate = 1.0 M
Concentration of HCl must add = x
pH = 4.74 + log (1-x) / (2+x) = 4.11
x = concentration of HCl must be added = 0.43 M
number of moles of HCl = M * V = 0.43 * 1 = 0.43 mol
mass of HCl must be added = 0.43 * 36.5 = 15.7 g