Answer:
x = 100 * 1.1897 = 118.97 %, which is > 100 meaning that all of the HClO2 dissociates
Explanation:
Recall that , depression present in freezing point is calculated with the formulae = solute particles Molarity x KF
0.3473 = m * 1.86
Solving, m = 0.187 m
Moles of HClO2 = mass / molar mass = 5.85 / 68.5 = 0.0854 mol
Molality = moles / mass of water in kg = 0.0854 / 1 = 0.0854 m
Initial molality
Assuming that a % x of the solute dissociates, we have the ICE table:
HClO2 H+ + ClO2-
initial concentration: 0.0854 0 0
final concentration: 0.0854(1-x/100) 0.0854x/100 0.0854x / 100
We see that sum of molality of equilibrium mixture = freezing point molality
0.0854( 1 - x/100 + x/100 + x/100) = 0.187
2.1897 = 1 + x / 100
x = 100 * 1.1897 = 118.97 %, which is > 100 meaning that all of the HClO2 dissociates
Answer:
A.
Explanation:
The number of the them will result in A.
I need a little more context but I believe you are correct
Answer:
Activation energy of phenylalanine-proline peptide is 66 kJ/mol.
Explanation:
According to Arrhenius equation-
, where k is rate constant, A is pre-exponential factor,
is activation energy, R is gas constant and T is temperature in kelvin scale.
As A is identical for both peptide therefore-
![\frac{k_{ala-pro}}{k_{phe-pro}}=e^\frac{[E_{a}^{phe-pro}-E_{a}^{ala-pro}]}{RT}](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7Bala-pro%7D%7D%7Bk_%7Bphe-pro%7D%7D%3De%5E%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-E_%7Ba%7D%5E%7Bala-pro%7D%5D%7D%7BRT%7D)
Here
, T = 298 K , R = 8.314 J/(mol.K) and 
So, ![\frac{0.05}{0.005}=e^{\frac{[E_{a}^{phe-pro}-(60000J/mol)]}{8.314J.mol^{-1}.K^{-1}\times 298K}}](https://tex.z-dn.net/?f=%5Cfrac%7B0.05%7D%7B0.005%7D%3De%5E%7B%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-%2860000J%2Fmol%29%5D%7D%7B8.314J.mol%5E%7B-1%7D.K%5E%7B-1%7D%5Ctimes%20298K%7D%7D)
(rounded off to two significant digit)
So, activation energy of phenylalanine-proline peptide is 66 kJ/mol