A solid is hard and the molecules are packed together, a liquid can move around freely because the molecules aren't as packed together :)
We do a heat balance to solve this:
(m cp ΔT)water = -(m cp ΔT)metal
100.8 (4.18) (27 - 22) = -65 (cp)(27-100)
cp = 100.8 (4.18) (27 - 22) / (-65 (27-100))
cp = 0.44 J/ (°C × g)
The specific heat of the metal is 0.44 J/ (°C × g)
B. They work against a strong gravitational force
Answer:
Kc = 50.5
Explanation:
We determine the reaction:
H₂ + I₂ ⇄ 2HI
Initially we have 0.001 molesof H₂
and 0.002 moles of I₂
If we have produced 0.00187 moles of HI in the equilibrium we have to know, how many moles of I₂ and H₂, have reacted.
H₂ + I₂ ⇄ 2HI
In: 0.001 0.002 -
R: x x 2x
Eq: 0.001-x 0.002-x 0.00187
x = 0.00187/2 = 9.35×10⁻⁴ moles that have reacted
So in the equilibrium we have:
0.001 - 9.35×10⁻⁴ = 6.5×10⁻⁵ moles of H₂
0.002 - 9.35×10⁻⁴ = 1.065×10⁻³ moles of I₂
Expression for Kc is = (HI)² / (H₂) . (I₂)
0.00187 ² / 6.5×10⁻⁵ . 1.065×10⁻³ = 50.5
As can be seen in the attached image, α-pyrone has a highly electrophilic carbon atom, since it is attached to two oxygen atoms that are electronegative and subtract electrical charge from the carbon, leaving it with a <u>positive partial charge</u>. By virtue of the above, <u>the bromine atoms, which have an important electron density that makes them good nucleophiles, will be attracted to the aforementioned carbon due to their positive charge</u>, thus favoring the substitution product to a greater extent than that of addition.