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Nonamiya [84]
3 years ago
9

An experiment shows that a 236 mL gas sample has a mass of 0.443 g at a pressure of 740 mmHg and a temperature of 22 ∘C. What is

the molar mass of the gas?
Chemistry
1 answer:
aleksley [76]3 years ago
3 0

Answer:

49.2 g/mol

Explanation:

Let's first take account of what we have and convert them into the correct units.

Volume= 236 mL x (\frac{1 L}{1000 mL}) = .236 L

Pressure= 740 mm Hg x (\frac{1 atm}{760 mm Hg})= 0.97 atm

Temperature= 22C + 273= 295 K

mass= 0.443 g

Molar mass is in grams per mole, or MM= \frac{mass}{moles} or MM= \frac{m}{n}. They're all the same.

We have mass (0.443 g) we just need moles. We can find moles with the ideal gas constant PV=nRT. We want to solve for n, so we'll rearrange it to be

n=\frac{PV}{RT}, where R (constant)= 0.082 L atm mol-1 K-1

Let's plug in what we know.

n=\frac{(0.97 atm)(0.236 L)}{(0.082)(295K)}

n= 0.009 mol

Let's look back at MM= \frac{m}{n} and plug in what we know.

MM= \frac{0.443 g}{0.009 mol}

MM= 49.2 g/mol

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We will use de Broglie's equation.

λ = h / m × v

λ = 6.63 × 10⁻³⁴ J.s / 1.67 × 10⁻²⁷ kg × 490 m/s = 8.10 × 10⁻¹⁰ m

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<u>The balanced chemical equation for the combustion of heptane</u>:

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Given: The standard enthalpy of formation (\Delta H _{f}^{\circ }) for: C₇H₁₆ (l) = -187.8 kJ/mol, O₂ (g) = 0 kJ/mol, CO₂ (g) = -393.5 kJ/mol, H₂O (l) = -286 kJ/mol

<u>To calculate the standard enthalpy of reaction (\Delta H _{r}^{\circ }) can be calculated by the Hess's law</u>:

\Delta H _{r}^{\circ } = \left [\sum \nu \cdot\Delta H _{f}^{\circ }(products)  \right ] - \left [\sum \nu\cdot\Delta H _{f}^{\circ }(reactants)  \right ]

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\left [ 7\times \Delta H _{f}^{\circ }\left (CO_{2}\right )+ 8\times \Delta H _{f}^{\circ }\left (H_{2}O \right )\right ]

- \left [1\times \Delta H _{f}^{\circ }\left (C_{7}H_{16}\right ) +11\times \Delta H _{f}^{\circ }\left (O_{2} \right ) \right ]

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-\left [1\times \left (-187.8 kJ/mol \right ) +11\times \left (0 kJ/mol \right ) \right ]

⇒ \Delta H _{r}^{\circ } = \left [ \left (-2754.5 \right )+ \left (-2288 \right )\right ]\left -[ \left (-187.8 \right ) +\left (0 \right )\right ]

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We use the ideal gas equation: P.V = n.R.T

⇒ ΔH-ΔE=Δ(PV) = Δn.R.T

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Δn = number of moles of gaseous products - number of moles of gaseous reactants = (7)- (11) = (-4)

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