Which statement accurately describes the reactants of a reaction? new substances that are present at the end of a reaction subst
2 answers:
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Answer:
Explanation:
(a) Part 1: reaction. This is a nucleophilic substitution reaction in which we have two steps. Firstly, chlorine, a good leaving group, leaves the carbon skeleton to form a relatively stable secondary carbocation. This carbocation is then attacked by the hydroxide anion, our nucleophile, to form the final product.
To summarize, this mechanism takes places in two separate steps. The mechanism is attached below.
Part 2: reaction. This is a nucleophilic substitution reaction in which we have one step. Our nucleophile, hydroxide, attacks the carbon and then chlorine leaves simultaneously without an intermediate carbocation being formed.
The mechanism is attached as well.
(b) The rate determining step is the slow step. Formation of the carbocation has the greatest activation energy, so this is our rate determining step for . For
, we only have one step, so the rate determining step is the attack of the nucleophile and the loss of the leaving group.
<u>Answer:</u> The mass defect for the formation of phosphorus-31 is 0.27399
<u>Explanation:</u>
Mass defect is defined as the difference in the mass of an isotope and its mass number.
The equation used to calculate mass defect follows:
where,
= number of protons
= mass of one proton
= number of neutrons
= mass of one neutron
M = mass number of element
We are given:
An isotope of phosphorus which is
Number of protons = atomic number = 15
Number of neutrons = Mass number - atomic number = 31 - 15 = 16
Mass of proton = 1.00728 amu
Mass of neutron = 1.00866 amu
Mass number of phosphorus = 30.973765 amu
Putting values in above equation, we get:
Hence, the mass defect for the formation of phosphorus-31 is 0.27399