The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴ ![8.3 = 8.3 + log \frac{[0.005]}{[0.005]}](https://tex.z-dn.net/?f=8.3%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005%5D%7D%7B%5B0.005%5D%7D)
<em> </em>inverse log 0 = ![\frac{[B]}{[A]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D)
![\frac{[B]}{[A]} = 1](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D%20%3D%201)
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
![pH = 8.3 + log \frac{[0.005-0.003]}{[0.005+0.003]}\\pH = 8.3 + log \frac{[0.002]}{[0.008]}\\\\pH = 8.3 + log {0.25}\\\\pH = 8.3 + (-0.62)\\pH = 7.69](https://tex.z-dn.net/?f=pH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005-0.003%5D%7D%7B%5B0.005%2B0.003%5D%7D%5C%5CpH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.002%5D%7D%7B%5B0.008%5D%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20log%20%7B0.25%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20%28-0.62%29%5C%5CpH%20%3D%207.69)
Therefore, the new pH is 7.69.
Learn more about pH here:
brainly.com/question/24595796
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Answer: Option (b) is the correct answer.
Explanation:
The given chemical reaction shows that hydrogen cyanide acid has been added to water which results in the formation of hydronium ion and cyanide ion.
Also, when we add a base like sodium hydroxide (NaOH) to HCN then it will help in accepting a proton (
) from hydrogen cyanide. As a result, formation of
anion will be rapid and easy.
This will make the system not to do any extra work. So, amount of work done by system will decrease.
Thus, we can conclude that out of the given options, add solid NaOH to the reaction (assume no volume change) will decrease the amount of work the system could perform.