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ahrayia [7]
3 years ago
11

1. What volume of toluene do you need to add to 1 mL of ethyl acetate to make an equi-molar mixture? The density of ethyl acetat

e (C4H8O2) is 0.898 g/mL and the density of toluene (C7H8) is 0.867 g/mL.
Chemistry
1 answer:
galben [10]3 years ago
4 0

Answer:

1.06 mL of toluene will be needed.

Explanation:

Equi-molar mixture means equal moles of all the components.

as given the volume of ethyl acetate = 1mL

Density of ethyl acetate = 0.898 g/mL

The relation between density, mass and volume is :

density=\frac{mass}{volume}

mass=volumeXdensity

mass of ethyl acetate present = 1mL X 0.898g/mL = 0.598 grams

the moles are related to mass as:

moles=\frac{mass}{molarmass}

For ethyl acetate molar mass = 4X12+8X1+2X16= 88g/mol

moles of ethyl acetate will be:

moles=\frac{0.898}{88}= 0.01mol

So we need 0.01 moles of toluene also

For 0.01 moles the mass of toluene required = 0.01 X molar mass of toluene

mass required = 0.01 X 92=0.92grams

for 0.92 grams of toluene volume required will be:

volume=\frac{mass}{density}=\frac{0.92}{0.867}= 1.06mL

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A mixture of CS2(g) and excess O2(g) is placed in a 10 L reaction vessel at 100.0 ∘C and a pressure of 3.10 atm . A spark causes
ziro4ka [17]

Answer:

PCO2  = 0.6 25 atm

PSO2  = 1.2 75 atm

PO2 = 0.6  atm

Explanation:

Step 1: Data given

Volume = 10.0 L

Temperature = 100.0 °C

Pressure = 3.10 °C

After reaction, the temperature returns to 100.0 ∘C, and the mixture of product gases (CO2, SO2, and unreacted O2) is found to have a pressure of 2.50 atm

Step 2: The balanced equation

CS2(g)+3O2(g)→CO2(g)+2SO2(g)

Step 3: Name the reactants and products

a = CS2

b = O2 before reaction

c = CO2

d = SO2

e = nS O2 after reaction with n = the number of moles

Step 4: Calculate moles before reaction

PV = nRT

n = PV/(RT)

(na + nb) = (3.10atm) * (10.0L) / ((0.08206 Latm/moleK) * (373.15K))

(na + nb) = 1.0124

Step 5: Calculate moles after reaction

PV = nRT

n = PV/(RT)

nc + nd + ne) = PV/(RT) = (2.50 atm)*(10.0L) / ((0.08206 Latm/moleK)*(373.15K))

(nc + nd + ne) = 0.816 moles

Step 6: Calculate mol fraction

For  1 mole CS2 we need 3 moles O2  to produce 1 mole of CO2 and 2 moles of SO2

moles O2 remaining = ne = nb - 3na

moles CO2 produced = nc = na

moles SO2 producted = nd = 2na

(nc + nd + ne) = 0.816 moles = nb - 3na + na + 2na = 0.816

nb = 0.816

. (na + nb) = 1.0124

na = 1.0124 moles - 0.816 moles = 0.208

which leads to  

nc = na = 0.208

nd = 2na = 2*0.208 = 0.416

ne = 0.816 - 3*0.208 = 0.192

mole fraction CO2 = 0.208 / (0.208 + 0.416 + 0.192) = 0.25

mole fraction SO2 = 0.416 / (0.208 + 0.416 + 0.192) = 0.5 1

mole fraction O2 = 0.192 /(0.208 + 0.416 + 0.192) = 0.24

Step 6: Calculate partial pressure

PCO2 = 0.25 * 2.50 atm = 0.6 25 atm

PSO2 = 0.51 * 2.50 atm = 1.2 75 atm

PO2 = 0.24 * 2.50 atm = 0.6  atm

Step 7: Control results

now let's verify a couple of things

PV = nRT

P = nRT/V

before rxn

P = (0.208 + 0.816) * (0.08206 L*atm/mole*K) * (373.15K) / (10.0L) ≈ 3.10 atm

after rxn

P = ((0.208 +0.416+0.192) * (0.08206 L*atm/mole*K) * (373.15K) / (10.0L) ≈ 2.50 atm

8 0
3 years ago
How many moles of silicon are in 5.9 X 10 to the 24 power atoms of silicon​
Dimas [21]

Answer:

9.79740949850 moles

Explanation:

  • 1 mole = Avogardo's Number <<6.022 E 23 <<particles, atoms, etc.>>
  • This problem can be solved using dimensional analysis by multiplying atoms (5.9E24 atoms) by (1) mole and then dividing the number by Avogardo's number (6.022 E 23 atoms).
  • Note: E = * 10

Side Note: Please let me know if you need any clarifications about this!

8 0
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What is the ionic formula of the compound formed by Co3+ and the phosphorus ion? What is the name of the compound formed based o
klasskru [66]

Answer: The ionic formula of compound is CoP and the name is cobalt phosphide.

Explanation:

For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.

Here element Co is having an oxidation state of +3 called as Co^{3+} cation and phosphprous forms P^{3-} anion with oxidation state of -3. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral CoP

The nomenclature of ionic compounds is given by:

1. Positive is written first followed by the oxidation state of metal in roman numerals in square brackets.

2. The negative ion is written next and a suffix is added at the end of the negative ion. The suffix written is '-ide'.

Thus the name of CoP is cobalt phosphide.

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3 years ago
Which of the following did Mendeleev not believe in because he could not see them?
Zigmanuir [339]

Answer:atoms

Explanation:

6 0
3 years ago
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