Answer:
Explanation:
The principle applied is the Markovnikoff's rule which states that when hydrogen chloride adds to a double bond, the hydrogen atoms join to the carbon that already has the most hydrogen atoms bonded to it. The rule wa postulated by a russian chemist known as Vladimir Markovnikoff.
In the markovnikoff's rule, there are sveral conditions that must be met, one of them is that no free radicals must be involved.
The reaction and the structure of the product is as shown in the attachment.
Answer:
0.4694 moles of CrCl₃
Explanation:
The balanced equation is:
Cr₂O₃(s) + 3CCl₄(l) → 2CrCl₃(s) + 3COCl₂(aq)
The stoichiometry of the equation is how much moles of the substances must react to form the products, and it's represented by the coefficients of the balanced equation. So, 1 mol of Cr₂O₃ must react with 3 moles of CCl₄ to form 2 moles of CrCl₃ and 3 moles of COCl₂.
The stoichiometry calculus must be on a moles basis. The compounds of interest are Cr₂O₃ and CrCl₃. The molar masses of the elements are:
MCr = 52 g/mol
MCl = 35.5 g/mol
MO = 16 g/mol
So, the molar mass of the Cr₂O₃ is = 2x52 + 3x35.5 = 210.5 g/mol.
The number of moles is the mass divided by the molar mass, so:
n = 49.4/210.5 = 0.2347 mol of Cr₂O₃.
For the stoichiometry:
1 mol of Cr₂O₃ ------------------- 2 moles of CrCl₃
0.2347 mol of Cr₂O₃----------- x
By a simple direct three rule:
x = 0.4694 moles of CrCl₃
There are 4 lone pairs of electrons present in the carbon dioxide molecule
