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MA_775_DIABLO [31]

2 years ago

14

Pls help with these two questions~-~

1 answer:

RSB [31]2 years ago

4 0

The answer is geometry and geography you add math subtract read and follow instructions

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An electrochemical cell at 25°C is composed of pure copper and pure lead solutions immersed in their respective ionis. For a 0.6

ExtremeBDS [4]

Answer :

(a) The concentration of $Pb^{2+}$ is, 0.0337 M

(b) The concentration of $Pb^{2+}$ is, $6.093\times 10^{32}M$

Solution :

<u>(a) As per question, lead is oxidized and copper is reduced.</u>

The oxidation-reduction half cell reaction will be,

Oxidation half reaction: $Pb\rightarrow Pb^{2+}+2e^-$

Reduction half reaction: $Cu^{2+}+2e^-\rightarrow Cu$

The balanced cell reaction will be,

$Pb(s)+Cu^{2+}(aq)\rightarrow Pb^{2+}(aq)+Cu(s)$

Here lead (Pb) undergoes oxidation by loss of electrons, thus act as anode. Copper (Cu) undergoes reduction by gain of electrons and thus act as cathode.

First we have to calculate the standard electrode potential of the cell.

$E^o_{[Pb^{2+}/Pb]}=-0.13V$

$E^o_{[Cu^{2+}/Cu]}=+0.34V$

$E^o=E^o_{[Cu^{2+}/Cu]}-E^o_{[Pb^{2+}/Pb]}$

$E^o=0.34V-(-0.13V)=0.47V$

Now we have to calculate the concentration of $Pb^{2+}$ .

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Pb^{2+}]}{[Cu^{2+}]}$

where,

n = number of electrons in oxidation-reduction reaction = 2

$E_{cell}$ = 0.507 V

Now put all the given values in the above equation, we get:

$0.507=0.47-\frac{0.0592}{2}\log \frac{[Pb^{2+}]}{(0.6)}$

$[Pb^{2+}]=0.0337M$

Therefore, the concentration of $Pb^{2+}$ is, 0.0337 M

<u>(b) As per question, lead is reduced and copper is oxidized.</u>

The oxidation-reduction half cell reaction will be,

Oxidation half reaction: $Cu\rightarrow Cu^{2+}+2e^-$

Reduction half reaction: $Pb^{2+}+2e^-\rightarrow Pb$

The balanced cell reaction will be,

$Cu(s)+Pb^{2+}(aq)\rightarrow Cu^{2+}(aq)+Pb(s)$

Here Copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.

First we have to calculate the standard electrode potential of the cell.

$E^o_{[Pb^{2+}/Pb]}=-0.13V$

$E^o_{[Cu^{2+}/Cu]}=+0.34V$

$E^o=E^o_{[Pb^{2+}/Pb]}-E^o_{[Cu^{2+}/Cu]}$

$E^o=-0.13V-(0.34V)=-0.47V$

Now we have to calculate the concentration of $Pb^{2+}$ .

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Cu^{2+}]}{[Pb^{2+}]}$

where,

n = number of electrons in oxidation-reduction reaction = 2

$E_{cell}$ = 0.507 V

Now put all the given values in the above equation, we get:

$0.507=-0.47-\frac{0.0592}{2}\log \frac{(0.6)}{[Pb^{2+}]}$

$[Pb^{2+}]=6.093\times 10^{32}M$

Therefore, the concentration of $Pb^{2+}$ is, $6.093\times 10^{32}M$

6 0

2 years ago

You need to produce a buffer solution that has a pH of 5.31. You already have a solution that contains 10. mmol (millimoles) of

Karolina [17]

Answer:

37 mmol of acetate need to add to this solution.

Explanation:

Acetic acid is an weak acid. According to Henderson-Hasselbalch equation for a buffer consist of weak acid (acetic acid) and its conjugate base (acetate)-

$pH=pK_{a}(acetic acid)+log[\frac{mmol of CH_{3}COO^{-}}{mmol of CH_{3}COOH }]$

Here pH is 5.31, $pK_{a}$ (acetic acid) is 4.74 and number of mmol of acetic acid is 10 mmol.

Plug in all the values in the above equation:

$5.31=4.74+log[\frac{mmol of CH_{3}COO^{-}}{10}]$

or, mmol of $CH_{3}COO^{-}$ = 37

So 37 mmol of acetate need to add to this solution.

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2 years ago

Kendra and Jordan gather firewood. The wood is cool to the touch, but the campfire they make warms their hands. Which statement

Free_Kalibri [48]

Answer:

D

Explanation:

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2 years ago

El nino was tracked by?<br>sealab 1<br>jason1<br>topex/Poseidon <br>trieste

IrinaK [193]

I remember this from a week ago. The answer was topex/poseidon

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2 years ago

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The Groups 1 and 2 on the periodic table contain what atom type?

Bumek [7]

Non metals
and metals

8 0

2 years ago

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