The rate law depicts the effect of concentration on reaction rate. Second mechanism 2NO(g) ⇄ N₂O₂(g) [fast], N₂O₂(g) + O₂(g) → 2NO₂(g) [slow] is most reasonable. Thus, option b is correct.
<h3>What is rate law?</h3>
Rate law and equation give the rate at which the reaction takes place under the influence of the concentration of the reactants. The balanced chemical reaction is given as,
2NO(g) + O₂(g) → 2NO₂(g)
The rate of the equation is given as,
rate = k [NO]² [O₂]
In a multi-step chemical reaction, the slowest step is the rate-determining step. The second mechanism is given as,
2NO (g) → N₂O₂ (g) [fast]
N₂O₂(g) +O₂(g) → 2NO₂ (g) [slow]
Rate is given as,
rate = k [N₂O₂] [O₂]
Therefore, option b. the second mechanism is the most reasonable.
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Answer:
water, when the metastable state is reached, is cooled below the zero temperature. It freezes abruptly. this is called metastable. They are not at equilibrium per se; as at negative temperatures the only equilibrium state of water is ice.
Explanation:
N₂O₄ (g) ⇌ 2 NO₂ (g)
Kc = [ NO₂ ]² / [ N₂O₄ ]
4.2 = [ 0.785 ] [ N₂O₄ ]
[ N₂O₄ ] = 4.2 / 0.785
[N₂O₄ ] = 5.350 M
hope this helps!
<span>This family of elements is headed by boron. In this case, atomic size increases as one goes down the periodic table, as there are more electrons in each successive element needed to fill the outer shells. As such, thallium, at the lowest level of the group 3a column, will have the largest atomic size.</span>