ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹
The answer is 10-12. The relationship of pH and [H+] is pH = -lg[H+]. And the higher pH, the stronger base is. So the strongest base has the lowest concentration of H+.
The system is isothermal, so we use the formula:
(delta)G = (delta)H - T (delta) S
Plugging in the given values:
(delta)G = -220 kJ/ mol - (1000K) (-0.05 kJ/mol K)
(delta)G = -170 kJ/mol
If we take a basis of 1 mol, the answer is
D. -170 kJ
After 3 half-lives, 125 grams of the parent isotope will remain.
Use your head or a formula website.
