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2 years ago

Did Chelate compounds increase the rate of reaction?

Chemistry

1 answer:

Viefleur [7K]2 years ago

7 0

Answer:

Chelate, any of a class of coordination or complex compounds consisting of a central metal atom attached to a large molecule, called a ligand, in a cyclic or ring structure. An example of a chelate ring occurs in the ethylenediamine-cadmium complex:

The ethylenediamine ligand has two points of attachment to the cadmium ion, thus forming a ring; it is known as a didentate ligand. (Three ethylenediamine ligands can attach to the Cd2+ ion, each one forming a ring as depicted above.) Ligands that can attach to the same metal ion at two or more points are known as polydentate ligands. All polydentate ligands are chelating agents.

Chelates are more stable than nonchelated compounds of comparable composition, and the more extensive the chelation—that is, the larger the number of ring closures to a metal atom—the more stable the compound. This phenomenon is called the chelate effect; it is generally attributed to an increase in the thermodynamic quantity called entropy that accompanies chelation. The stability of a chelate is also related to the number of atoms in the chelate ring. In general, chelates containing five- or six-membered rings are more stable than chelates with four-, seven-, or eight-membered rings.

Explanation:

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For A: The equation is $_{92}^{238}\textrm{U}\rightarrow _{90}^{234}\textrm{Th}+_2^4\alpha$

For B: The equation is $_{94}^{239}\textrm{Pu}\rightarrow _{92}^{235}\textrm{U}+_2^4\alpha$

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Explanation:

Alpha decay process is the process in which nucleus of an atom disintegrates into two particles. The first one which is the alpha particle consists of two protons and two neutrons. This is also known as helium nucleus. The second particle is the daughter nuclei which is the original nucleus minus the alpha particle released.

$_Z^A\textrm{X}\rightarrow _{Z-2}^{A-4}\textrm{Y}+_2^4\alpha$

Beta decay process is defined as the process the neutrons get converted into an electron and a proton. The released electron is known as the beta particle. In this process, the atomic number of the daughter nuclei gets increased by a factor of 1 but the mass number remains the same.

$_Z^A\textrm{X}\rightarrow _{Z+1}^A\textrm{Y}+_{-1}^0\beta$

For A: Uranium-238 emits an alpha particle

The nuclear equation for this process follows:

$_{92}^{238}\textrm{U}\rightarrow _{90}^{234}\textrm{Th}+_2^4\alpha$

For B: Plutonium-239 emits an alpha particle

The nuclear equation for this process follows:

$_{94}^{239}\textrm{Pu}\rightarrow _{92}^{235}\textrm{U}+_2^4\alpha$

For C: Thorium-239 emits a beta particle

The nuclear equation for this process follows:

$_{90}^{239}\textrm{Th}\rightarrow _{91}^{235}\textrm{Pa}+_{-1}^0\beta$

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