Answer:
The order of solubility is AgBr < Ag₂CO₃ < AgCl
Explanation:
The solubility constant give us the molar solubilty of ionic compounds. In general for a compound AB the ksp will be given by:
Ksp = (A) (B) where A and B are the molar solubilities = s² (for compounds with 1:1 ratio).
It follows then that the higher the value of Ksp the greater solubilty of the compound if we are comparing compounds with the same ionic ratios:
Comparing AgBr: Ksp = 5.4 x 10⁻¹³ with AgCl: Ksp = 1.8 x 10⁻¹⁰, AgCl will be more soluble.
Comparing Ag2CO3: Ksp = 8.0 x 10⁻¹² with AgCl Ksp = AgCl: Ksp = 1.8 x 10⁻¹⁰ we have the complication of the ratio of ions 2:1 in Ag2CO3, so the answer is not obvious. But since we know that
Ag2CO3 ⇄ 2 Ag⁺ + CO₃²₋
Ksp Ag2CO3 = 2s x s = 2 s² = 8.0 x 10-12
s = 4 x 10⁻12 ∴ s= 2 x 10⁻⁶
And for AgCl
AgCl ⇄ Ag⁺ + Cl⁻
Ksp = s² = 1.8 x 10⁻¹⁰ ∴ s = √ 1.8 x 10⁻¹⁰ = 1.3 x 10⁻⁵
Therefore, AgCl is more soluble than Ag₂CO₃
The order of solubility is AgBr < Ag₂CO₃ < AgCl
Water is a pure substance because it is not refined like the other materials. Hope this helps!!!
Answer:
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The molar mass of the compound:
If the solution has an osmotic pressure of 8.44 torr, then the molar mass of the unknown non-electrolyte is 223.14 g.
What is osmosis?
- Osmosis is defined as the flow of solvent molecules through semi-permeable membrane.
- Osmotic pressure is the pressure applied to stop the flow of solvent molecules.
- It is a colligative property that means osmotic pressure depends on the number of solute particles .
Therefore,
π ( for electrolytes)
Where, π= Osmotic pressure
i = Van 't Hoff factor
n= moles
R= Gaseous constant = 62.363577 L torr
T= Temperature
V= Volume of solution
Given:
T= 298K
V= 150 mL= 0.150 L
Given mass of unknown electrolyte= 15.2 mg = 15.2 x g
Osmotic pressure= 8.44 torr
Molar mass= ?
For non-electrolytes:
πV = n RT
πV=RT
Calculations:
Putting the given values in the formula:
8.44 x 0.150 =15.2 x / M x 62.36 x 298
1.266 = 282.5/M
M = 282.5/1.266
M = 223.14 g
Therefore,
The molar mass of the unknown non-electrolyte is 223.14g.
Learn more about Osmotic pressure here,
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