Explanation:
Lithium diisopropylamide (LDA) is used in many organic synthesis and is a strong base. It is prepared by the acid base reaction of N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) and butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ).
The equation is show below as:
[(CH₃)₂CH]₂NH + Li⁺⁻CH₂CH₂CH₂CH₃ ⇒ [(CH₃)₂CH]₂N⁻Li⁺ + CH₃CH₂CH₂CH₃
N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) is a weaker acid and hence, LDA ( [(CH₃)₂CH]₂N⁻Li⁺ ) is stronger base. (Weaker acid has stronger conjugate base)
Butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ) is a very strong base and hence, butane ( CH₃CH₂CH₂CH₃ ) is a very weak acid. (Strong base has weaker conjugate acid)
Answer:
185.05 g.
Explanation
Firstly, It is considered as a stichiometry problem.
From the balanced equation: 2LiCl → 2Li + Cl₂
It is clear that the stichiometry shows that 2.0 moles of LiCl is decomposed to give 2.0 moles of Li metal and 1.0 moles of Cl₂, which means that the molar ratio of LiCl : Li is (1.0 : 1.0) ratio.
We must convert the grams of Li metal (30.3 g) to moles (n = mass/atomic mass), atomic mass of Li = 6.941 g/mole.
n = (30.3 g) / (6.941 g/mole) = 4.365 moles.
Now, we can get the number of moles of LiCl that is needed to produce 4.365 moles of Li metal.
Using cross multiplication:
2.0 moles of LiCl → 2.0 moles of Li, from the stichiometry of the balanced equation.
??? moles of LiCl → 4.365 moles of Li.
The number of moles of LiCl that will produce 4.365 moles of Li (30.3 g) is (2.0 x 4.365 / 2.0) = 4.365 moles.
Finally, we should convert the number of moles of LiCl into grams (n = mass/molar mass).
Molar mass of LiCl = 42.394 g/mole.
mass = n x molar mass = (4.365 x 42.394) = 185.05 g.
The properties of compounds are different, and in some cases very different, from those of the elements that compose them. This is because elements combine in compounds to become completely different substances with unique properties.
Compounds contain atoms of different elements chemically bonded in fixed ratios. An element is a pure chemical substance made up of atoms of the same kind. Compounds contain different elements in fixed ratios, arranged in a defined way by chemical bonds.
This is caused by different base properties where each element has a different number. Due to the number of electrons and differences in shell and valence electrons, different elements bond differently to certain other elements.
Compounds:
is composed of atoms of two or more different elements bonded together, and
can be broken down into simpler types of matter (elements) by chemical (rather than physical) means. from its components, and.
always contains the same proportions of atomic components.
Learn more about elements combine here;
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