Molar mass (CaCl2) = 40.1 +2*35.5 = 111.1 g/mol
Molar mass (AlCl3) = 27.0 +3*35.5= 133.5 g/ mol
3CaCl2+Al2O3 -------->3CaO +2AlCl3
mole from reaction 3 mol 2 mol
mass from reaction 3mol* 111.1g/mol 2 mol*133.5g/mol
333.3 g 267.0 g
mass from problem 45.7 g x g
Proportion:
333.3 g CaCl2 ------- 267.0 g AlCl3
45.7 g CaCl2 -------- x g AlCl3
x=45.7*267.0/333.3= 36.6 g AlCl3
Explanation:
Starting moles of ethanol acid = 0.020 mol
At the equilibrium 50 % of the ethanol acid molecules reacted
∴ Moles of ethanol acid reacted = 0.020 mol * 50 %/100 %
= 0.010 mol
Moles of ethanol acid remain = 0.020 mol + 0.010 mol = 0.010 mol
Moles of the product 
gas formed are calculated as
0.010 mol CH3COOH * 1 mol / 2 mol CH3COOH
= 0.005 mol
Therefore at the equilibrium total moles of gas present in the vessel are 0.010 mol CH3COOH and 0.005 mol
That is total gas moles at equilibrium = 0.010 mol + 0.005 mol = 0.015 mol
Now Calculate the pressure :
0.020 mol gas has pressure of 0.74 atm therefore at the same condition what will be the pressure exerted by 0.015 mol gas
P1/n1 = P2/n2
P2 = P1*n2 / n1
= 0.74 atm * 0.015 mol / 0.020 mol
= 0.555 atm
First, we need to calculate moles of hydrazoic acid NH3:
moles NH3 = molarity * volume
= 0.15 m * 0.025 L
= 0.00375 moles
moles NaOH = molarity * volume
= 0.15 m * 0.015 L
= 0.00225 moles
after that we shoul get the total volume = 0.025L + 0.015L
= 0.04 L
So we can get the concentration of NH3 & NaOH by:
∴[NH3] = moles NH3 / total volume
= 0.00375 moles / 0.04 L
= 0.09375 M
∴[NaOH] = moles NaOH / total volume
= 0.00225 moles / 0.04 L
= 0.05625 M
then, when we have the value of Ka of NH3 so we can get the Pka value from:
Pka = -㏒Ka
= - ㏒ 1.9 x10^-5
= 4.7
finally, by using H-H equation we can get PH:
PH = Pka + ㏒[salt/ basic]
PH = 4.7 +㏒[0.05625/0.09375]
∴ PH = 4.48
Answer:
The reactants would appear at a higher energy state than the products.
Have a nice day!
