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PilotLPTM [1.2K]
2 years ago
6

Which elements can have expanded octets?

Chemistry
1 answer:
PSYCHO15rus [73]2 years ago
7 0

Answer:

Sulfur, phosphorus, silicon, and chlorine are common examples of elements that form an expanded octet.

Explanation:

Phosphorus pentachloride (PCl5) and sulfur hexafluoride (SF6) are examples of molecules that deviate from the octet rule by having more than 8 electrons around the central atom

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Manganese dioxide (MnO2(s), Hf = –520.0 kJ) reacts with aluminum to form aluminum oxide (AI2O3(s), Hf = –1699.8 kJ/mol) and mang
Temka [501]

Answer : The enthalpy of the reaction = -1839.6 KJ

Solution : Given,

\Delta (H_{f})_{MnO_{2}} = -520.0 KJ/mole

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The balanced chemical reaction is,

3MnO_{2}(s)+4Al(s)\rightarrow 2Al_{2}O_{3}(s)+3Mn(s)

Formula used :

\Delta (H_{f})_{reaction}=\sum n(\Delta H_{f})_{product}-\sum n(\Delta H_{f})_{reactant}

\Delta (H_{f})_{reaction}=(2\times \Delta H_{Al_{2}O_{3}(s)}+3\times \Delta H_{Mn(s)} )-(3\times \Delta H_{MnO_{2}(s) }+4\times\Delta H_{Al}(s))

We know that the standard enthalpy of formation of the element is equal to Zero.

Therefore, the enthalpy of formation of (Mn) and (Al) is equal to zero.

Now, put all the values in above formula, we get

\Delta (H_{f})_{reaction}=[2moles\times (-1699.8 KJ/mole)}+3moles\times (0\text{ KJ/mole}})]-[(3moles\times(-520.0KJ/mole }+4moles\times(0\text{ KJ/mole})]

                        = (-3399.6) + (1560)

                        = -1839.6 KJ



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