Answer:
A and D are true , while B and F statements are false.
Explanation:
A) True. Since the standard gibbs free energy is
ΔG = ΔG⁰ + RT*ln Q
where Q= [P1]ᵃ.../([R1]ᵇ...) , representing the ratio of the product of concentration of chemical reaction products P and the product of concentration of chemical reaction reactants R
when the system reaches equilibrium ΔG=0 and Q=Keq
0 = ΔG⁰ + RT*ln Q → ΔG⁰ = (-RT*ln Keq)
therefore the first equation also can be expressed as
ΔG = RT*ln (Q/Keq)
thus the standard gibbs free energy can be determined using Keq
B) False. ΔG⁰ represents the change of free energy under standard conditions . Nevertheless , it will give us a clue about the ΔG around the standard conditions .For example if ΔG⁰>>0 then is likely that ΔG>0 ( from the first equation) if the temperature or concentration changes are not very distant from the standard conditions
C) False. From the equation presented
ΔG⁰ = (-RT*ln Keq)
ΔG⁰>0 if Keq<1 and ΔG⁰<0 if Keq>1
for example, for a reversible reaction ΔG⁰ will be <0 for forward or reverse reaction and the ΔG⁰ will be >0 for the other one ( reverse or forward reaction)
D) True. Standard conditions refer to
T= 298 K
pH= 7
P= 1 atm
C= 1 M for all reactants
Water = 55.6 M
Answer:
the reactants are 2h2 and 02. the products are 2h20
have a great day my friend ;)
<333
This type of chemical bond is called an ionic bond because the bond formed between two ions of opposite charge.
Answer: The hydroboration of an alkene occurs in TWO CONCERTED STEP which places the boron of the borane on the LESS SUBSTITUTED carbon of the double bond. The oxidizing agent then acts as a nucleophile, attacking the electrophilic BORON and resulting in the placement of a hydroxyl group on the attached carbon. Thus, the major product of the hydroboration oxidation reaction DOES NOT follow Markovnikov's rule.
Explanation:
Hydroboration is defined as the process which allows boron to attain the octet structure. This involves a two steps pathway which leads to the production of alcohol.
--> The first step: this involves the initiation of the addittion of borane to the alkene and this proceeds as a concerted reaction because bond breaking and bond formation occurs at the same time.
--> The second step: this involves the addition of boron which DOES NOT follow Markovnikov's rule( that is, Anti Markovnikov addition of Boron). This is so because the boron adds to the less substituted carbon of the alkene, which then places the hydrogen on the more substituted carbon.
Note: The Markovnikov rule in organic chemistry states that in alkene addition reactions, the electron-rich component of the reagent adds to the carbon atom with fewer hydrogen atoms bonded to it, while the electron-deficient component adds to the carbon atom with more hydrogen atoms bonded to it.
