a) when Kc = concentration of products / concentration of reactants
So according to the reaction equation:
Br2(g) + Cl2(g) → 2BrCl(g)
∴ Kc =[BrCl] ^2 / [Br2][Cl2]
b) when q = [BrCl]^2 / [Br2][Cl2]
and we have [BrCl] = 3 m
[Br2] = 1 m
[Cl2] = 1 m
So by substitution:
q= 3^2 / 1*1 = 9
- and we can see that q > Kc
the reaction is not at equilibrium that means there are more products and the reaction shifts to the left to increase the reactants and decrease the products to achieve equilibrium.
C) by using ICE table:
Br2(g) + Cl2(g) → 2BrCl (g)
initial 1 1 3
change -X -X +X
Equ (1-X) (1-X) (3+X)
when Kc = [Brcl]^2/[Cl2][Br2]
by substitution:
7 = (3+X)^2 / (1+X) (1+X) by solving this equation for X
∴X = 0.215
so at equilibrium:
∴ [Br2] = [Cl2] = 1-0.215 = 0.785 m
[BrCl] = 3+0.215 = 3.215 m
Answer:
1. Volume as STP = 755 L
2. Outside temperature = 255 K
3. Percentage yield = 70.5%
Explanation:
1. At STP, pressure = 101.3 kpa, temperature = 0°C or 273.15 K
Using the general gas equation :
P1V1/T1 = P2V2/T2
P1 = 620 kpa
V1 = 140 L
T1 = 37°C or (273.15 + 37) K = 310.15 K
P2 = 101.3 kpa
V2 = ?
T2 = 273.15 K
V2 = P1V1T2/P2T1
V2 = 620 × 140 × 273.15 / 101.3 × 310.15
V2 = 755 L
2. Using Charles' gas law:
V1/T1 = V2/T2
V1 = 2.5 L
T1 = 290 K
V2 = 2.2 L
T2 = ?
T2 = V2T1/VI
T2 = 2.2 × 290 / 2.5
T2 = 255 K
3. Equation of reaction : 2 Al + 3 CuSO4 ---> Al2 (SO4)3 + 3 Cu
From equation of the reaction, 2 moles of Al produces 3 moles of Cu
Molar mass of Al = 27 g; Molar mass of Cu = 63.5 g
2 moles of Al = 2 × 27 g = 54 g; 3 moles of Cu = 3× 63.5 = 190.5 g
54 g of Al produces 190.5 g of Cu
1.87 g of Al will produce 190.5/54 × 1.87 g of Cu = 6.60 g of Cu
Percentage yield = actual yield /theoretical yield × 100%
Percentage yield = 4.65/6.60 × 100%
Percentage yield = 70.5%
Answer:
THE NEW VOLUME OF THE OXYGEN GAS AT 28 PSI FROM 72.5 PSI IS 0.078 L.
Explanation:
Initial volume of the oxygen in the container = 30.0 mL = 30 / 000 L = 0.03 L
Initial pressure of the oxygen = 72.5 psi = 1 psi = 6890 pascal
Final pressure = 28 psi
Final volume = unknown
First convert the mL to L and since both pressures are in similar unit that is psi; there is no need converting them to pascal or other standard unit of pressure. They cancel each other out.
This question follows Boyle's equation of gas laws and mathematically it is written as:
P1 V1 = P2 V2
Re-arranging by making P2 the subject of the formula, we have:
V2 = P1 V1 / P2
V2 = 72,5 * 0.03 / 28
V2 = 2.175 /28
V2 = 0.0776 L
The new volume of the oxygen gas at a change in pressure from 72.5 psi to 28 psi is 0.078 L.
Atomic number for bromine is 35
