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iren2701 [21]
3 years ago
8

State at least three different properties of metallic compounds?

Chemistry
2 answers:
KATRIN_1 [288]3 years ago
7 0

Answer:

Very High melting and boiling points

Very Good Conductors of heat and electricity

Malleable (can be made into different shapes without breaking)

Ductile (can be molded into wiring)

Metallic luster (shiny)

Sometimes magnetic

Explanation:

horsena [70]3 years ago
5 0

Answer:

Very High melting and boiling points.

Very Good Conductors of heat and electricity.

Malleable (can be made into different shapes without breaking)

Ductile (can be molded into wiring)

Explanation:

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Answer:

a) ΔHºrxn = 116.3 kJ, ΔGºrxn = 82.8 kJ,  ΔSºrxn =  0.113 kJ/K

b) At 753.55 ºC or higher

c )ΔG =  1.8 x 10⁴ J

    K = 8.2 x 10⁻²

Explanation:

a)                                 C6H5−CH2CH3  ⇒  C6H5−CH=CH2  + H₂

ΔHf kJ/mol                    -12.5                           103.8                      0

ΔGºf kJ/K                        119.7                         202.5                      0

Sº J/mol                          255                          238                      130.6*

Note: This value was not given in our question, but is necessary and can be found in standard handbooks.

Using Hess law to calculate  ΔHºrxn we have

ΔHºrxn  = ΔHfº C6H5−CH=CH2 +  ΔHfº H₂ - ΔHºfC6H5−CH2CH3

ΔHºrxn =     103.8 kJ + 0 kJ  - (-12.5 kJ)

ΔHºrxn = 116.3 kJ

Similarly,

ΔGrxn = ΔGºf C6H5−CH=CH2 +  ΔGºfH₂ - ΔGºfC6H5CH2CH3

ΔGºrxn=   202.5 kJ + 0 kJ - 119.7 kJ  = 82.8 kJ

ΔSºrxn = 238 J/mol + 130.6 J/mol -255 J/K = 113.6 J/K = 0.113 kJ/K

b) The temperature at which the reaction is spontaneous or feasible occurs when ΔG becomes negative and using

ΔGrxn =  ΔHrxn -TΔS

we see that will happen when the term  TΔS  becomes greater than ΔHrxn since ΔS  is positive  , and so to sollve for T we will make ΔGrxn equal to zero and solve for T. Notice here we will make the assumption that  ΔºHrxn and ΔSºrxn remain constant at the higher temperature  and will equal the values previously calculated for them. Although this assumption is not entirely correct, it can be used.

0 = 116 kJ -T (0.113 kJ/K)

T = 1026.5 K  =  (1026.55 - 273 ) ºC = 753.55 ºC

c) Again we will use

                       ΔGrxn =  ΔHrxn -TΔS

to calculate ΔGrxn   with the assumption that ΔHº and ΔSºremain constant.

ΔG =  116.3 kJ - (600+273 K) x 0.113 kJ/K =  116.3 kJ - 873 K x 0.113 kJ/K

ΔG =  116.3 kJ - 98.6 kJ =  17.65 kJ = 1.8 x 10⁴ J ( Note the kJ are converted to J to necessary for the next part of the problem )

Now for solving for K, the equation to use is

ΔG = -RTlnK and solve for K

- ΔG / RT = lnK  ∴ K = exp (- ΔG / RT)

K = exp ( - 1.8 x 10⁴ J /( 8.314 J/K  x 873 K)) = 8.2 x 10⁻²

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Answer :

(A) The dissociation reaction of HC_2H_3O_2 will be:

HC_2H_3O_2(aq)\rightleftharpoons H^+(aq)+C_2H_3O_2^-(aq)

The equilibrium expression :

K_a=\frac{[H^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}

(B) The dissociation reaction of Co(H_2O)_6^{3+} will be:

Co(H_2O)_6^{3+}(aq)\rightleftharpoons H^+(aq)+Co(H_2O)_5(OH)^{2+}(aq)

The equilibrium expression :

K_a=\frac{[H^+][Co(H_2O)_5(OH)^{2+}]}{[Co(H_2O)_6^{3+}]}

(C) The dissociation reaction of CH_3NH_3^+ will be:

CH_3NH_3^+(aq)\rightleftharpoons H^+(aq)+CH_3NH_2(aq)

The equilibrium expression :

K_a=\frac{[H^+][CH_3NH_2]}{[CH_3NH_3^+]}

Explanation :

Equilibrium constant : It is defined as the equilibrium constant. It is defined as the ratio of concentration of products to the concentration of reactants.

The equilibrium expression for the reaction is determined by multiplying the concentrations of products and divided by the concentrations of the reactants and each concentration is raised to the power that is equal to the coefficient in the balanced reaction.

As we know that the concentrations of pure solids and liquids are constant that is they do not change. Thus, they are not included in the equilibrium expression.

(A) The dissociation reaction of HC_2H_3O_2 will be:

HC_2H_3O_2(aq)\rightleftharpoons H^+(aq)+C_2H_3O_2^-(aq)

The equilibrium expression of HC_2H_3O_2 will be:

K_a=\frac{[H^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}

(B) The dissociation reaction of Co(H_2O)_6^{3+} will be:

Co(H_2O)_6^{3+}(aq)\rightleftharpoons H^+(aq)+Co(H_2O)_5(OH)^{2+}(aq)

The equilibrium expression of Co(H_2O)_6^{3+} will be:

K_a=\frac{[H^+][Co(H_2O)_5(OH)^{2+}]}{[Co(H_2O)_6^{3+}]}

(C) The dissociation reaction of CH_3NH_3^+ will be:

CH_3NH_3^+(aq)\rightleftharpoons H^+(aq)+CH_3NH_2(aq)

The equilibrium expression of CH_3NH_3^+ will be:

K_a=\frac{[H^+][CH_3NH_2]}{[CH_3NH_3^+]}

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