$70 is what he would have left. Since each trip is $14 you would multiply that by the amount of times he went which was 11. 14x11 is $154. But you need what he has left so you take his total amount $224-$154 and get $70.
Part b.) 16 times. He has $224 total. You want to find out how many times he can go on the tool roads. We know the toll roads cost $14 each time. So you do $224/14 and get an even amount of 16. He would be able to use it 16 times before he have no money left.
The measure of an arc is the same as the measure of the central angle it subtends. The arc is marked 153°. The central angle (?°) has that same measure.