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Gnom [1K]
3 years ago
9

For a process Arightwards harpoon over leftwards harpoonB, at 25 °C there is 10% of A at equilibrium while at 75 °C, there is 80

% of A at equilibrium. Estimate enthalpy change of this reaction in kJ/mol
Chemistry
1 answer:
Lostsunrise [7]3 years ago
5 0

This question is describing the following chemical reaction at equilibrium:

A\rightleftharpoons B

And provides the relative amounts of both A and B at 25 °C and 75 °C, this means the equilibrium expressions and equilibrium constants can be written as:

K_1=\frac{90\%}{10\%}=9\\\\K_2=\frac{20\%}{80\%}  =0.25

Thus, by recalling the Van't Hoff's equation, we can write:

ln(K_2/K_1)=-\frac{\Delta H}{R}(\frac{1}{T_2} -\frac{1}{T_1} )

Hence, we solve for the enthalpy change as follows:

\Delta H=\frac{-R*ln(K_2/K_1)}{(\frac{1}{T_2} -\frac{1}{T_1} ) }

Finally, we plug in the numbers to obtain:

\Delta H=\frac{-8.314\frac{J}{mol*K} *ln(0.25/9)}{[\frac{1}{(75+273.15)K} -\frac{1}{(25+273.15)K} ] } \\\\\\\Delta H=4,785.1\frac{J}{mol}

Learn more:

  • brainly.com/question/10038290
  • brainly.com/question/19671384
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