Answer:
Phenols do not exhibit the same pka values as other alcohols;
They are generally more acidic.
Using the knowledge that hydrogen acidity is directly related to the stability of the anion formed, explain why phenol is more acidic than cyclohexane.
Explanation:
According to Bromsted=Lowry acid-base theory,
an acid is a substance that can release
ions when dissolved in water.
So, acid is a proton donor.
If the conjugate base of an acid is more stable then, that acid is a strong acid.
In the case of phenol,
the phenoxide ion formed is stabilized by resonance.

The resonance in phenoxide ion is shown below:
Whereas in the case of cyclohexanol resonance is not possible.
So, cyclohexanol is a weak acid compared to phenol.
Answer:
All atoms heavier than barium
Explanation:
In the periodic table, elements are divided into blocks. We have the;
s- block elements
p- block elements
d- block elements
f- block elements
However, immediately after Barium, we now encounter elements that have f-orbitals. Barium possesses a fully filled d-orbital. Hence after it, we see elements with 4f and 5f orbitals called the Lanthanides and actinides. The elements following the lanthanide and actinide series possess completely filled f-orbitals as inner orbitals.
Hence elements heavier than barium all possess f-orbitals.
Answer:
a) The equilibrium will shift in the right direction.
b) The new equilibrium concentrations after reestablishment of the equilibrium :
![[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M](https://tex.z-dn.net/?f=%5BSbCl_5%5D%3D%280.370-x%29%20M%3D%280.370-0.0233%29%20M%3D0.3467%20M)
![[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BSbCl_3%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
![[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BCl_2%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
Explanation:

a) Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.
This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.
On increase in amount of reactant

If the reactant is increased, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where more product formation is taking place. As the number of moles of
is increasing .So, the equilibrium will shift in the right direction.
b)

Concentration of
= 0.195 M
Concentration of
= 
Concentration of
= 
On adding more
to 0.370 M at equilibrium :

Initially
0.370 M
At equilibrium:
(0.370-x)M
The equilibrium constant of the reaction = 

The equilibrium expression is given as:
![K_c=\frac{[SbCl_3][Cl_2]}{[SbCl_5]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BSbCl_3%5D%5BCl_2%5D%7D%7B%5BSbCl_5%5D%7D)

On solving for x:
x = 0.0233 M
The new equilibrium concentrations after reestablishment of the equilibrium :
![[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M](https://tex.z-dn.net/?f=%5BSbCl_5%5D%3D%280.370-x%29%20M%3D%280.370-0.0233%29%20M%3D0.3467%20M)
![[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BSbCl_3%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
![[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BCl_2%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
Answer:
Limiting reactants or limiting reagents decide the amount of product formed and the amount of excess reagent used.
In an unknown liquid, the percentage composition with respect to carbon, hydrogen and iodine is 34.31%, 5.28% and 60.41% respectively.
Let the mass of liquid be 100 g thus, mass of carbon, hydrogen and oxygen will be 34.31 g, 5.28 g and 60.41 g respectively.
To calculate molecular formula of compound, convert mass into number of moles as follows:

Molar mass of carbon, hydrogen and iodine is 12 g/mol, 1 g/mol and 126.90 g/mol.
Taking the ratio:

Putting the values,

Thus, molecular formula of compound will be
.