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2 years ago

Magnesium carbonate and sulphuric acid react to form

Chemistry

2 answers:

Bas_tet [7]2 years ago

8 0

Answer:

The reaction is the following:

MgCO3 + H2SO4————————→ MgSO4 + CO2 + H2O

You will see evolution of carbon dioxide. It is an exothermic reaction.

Explanation:

What happens when magnesium carbonate reacts with acid?

Like many common group 2 metal carbonates, magnesium carbonate reacts with aqueous acids to release carbon dioxide and water:

MgCO3 + 2 HCl → MgCl2 + CO2 + H2O.

What products are produced when magnesium carbonate reacts with sulfuric acid?

Reactions of acids with carbonates

• Acid + carbonate → salt + water + carbon dioxide.

For example:

• Hydrochloric acid + copper carbonate → copper chloride + water + carbon dioxide.

Other carbonates also react with dilute acids. For example:

• Sulfuric acid + magnesium carbonate → magnesium sulfate + water + carbon dioxide.

Mekhanik [1.2K]2 years ago

4 0

Answer:

magnesium sulfate + water + carbon dioxide

Explanation:

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Consider the pka (3.75) of formic acid, h-cooh as a reference. with appropriate examples, show how inductive, dipole, and resona

Luden [163]

Formic acid is the simplest carboxylic acid with a structure of HCOOH and has a pka of 3.75. The pka refers to the acidity of the molecule, which in this example refers to the molecules ability to give up the proton of the O-H. A decrease in the pka value corresponds to an increase in acidity, or an increase in the ability to give up a proton. When an acid gives up a proton, the remaining anionic species (in this case HCOO-) is called the conjugate base, and an increase in the stability of the conjugate base corresponds to an increase in acidity.

The pka of a carboxylic can be affected greatly by the presence of various functional groups within its structure. An example of an inductive effect changing the pka can be shown with trichloroacetic acid, Cl3CCOOH. This molecule has a pka of 0.7. The decrease in pka relative to formic acid is due to the presence of the Cl3C- group, and more specifically the presence of the chlorine atoms. The electronegative chlorine atoms are able to withdraw the electron density away from the oxygen atoms and towards themselves, thus helping to stabilize the negative charge and stabilize the conjugate base. This results in an increase in acidity and decrease in pka.

The same Cl3CCOOH example can be used to explain how dipoles can effect the acidity of carboxylic acids. Compared to standard acetic acid, H3CCOOH with a pka of 4.76, trichloroacetic acid is much more acidic. The difference between these structures is the presence of C-Cl bonds in place of C-H bonds. A C-Cl bond is much more polar than a C-H bond, due the large electronegativity of the chlorine atom. This results in a carbon with a partial positive charge and a chlorine with a partial negative charge. In the conjugate base of the acid, where the molecule has a negative charge localized on the oxygen atoms, the dipole moment of the C-Cl bond is oriented such that the partial positive charge is on the carbon that is adjacent to the oxygen atoms containing the negative charge. Therefore, the electrostatic attraction between the positive end of the C-Cl dipole and the negative charge of the anionic oxygen helps to stabilize the entire species. This level of stabilization is not present in acetic acid where there are C-H bonds instead of C-Cl bonds since the C-H bonds do not have a large dipole moment.

To understand how resonance can affect the pka of a species, we can simply compare the pka of a simple alcohol such as methanol, CH3OH, and formic acid, HCOOH. The pka of methanol is 16, suggesting that is is a very weak acid. Once methanol gives up that proton to become the conjugate base CH3O-, the charge cannot be stabilized in any way and is simply localized on the oxygen atom. However, with a carboxylic acid, the conjugate base, HCOO-, can stabilize the negative charge. The lone pair electrons containing the charge on the oxygen atom are able to migrate to the other oxygen atom of the carboxylic acid. The negative charge can now be shared between the two electronegative oxygen atoms, thus stabilizing the charge and decreasing the pka.

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3 years ago

The unit cell for cr2o3 has hexagonal symmetry with lattice parameters a = 0.4961 nm and c = 1.360 nm. If the density of this ma

IRINA_888 [86]

To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

$A=6R^{2}\sqrt{3}$

Here, R is radius and is related to a as follows:

$R=\frac{a}{2}$

Putting the value in expression for area,

$A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}$

The value of a is 0.4961 nm

Since, $1 nm=10^{-7}cm$

Thus, $0.4961 nm=4.961\times 10^{-8} cm$

Putting the value,

$Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}$

Now, volume can be calculated as follows:

$V=Area\times c$

The value of c is 1.360 nm or $1.360\times 10^{-7} cm$

Putting the value,

$V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}$

now, number of atom in unit cell can be calculated by using the following formula:

$n=\frac{\rho N_{A}V_{c}}{A}$

Here, A is atomic mass of $Cr_{2}O_{3}$ is 151.99 g/mol.

Putting all the values,

$n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18$

Thus, there will be 18 $Cr_{2}O_{3}$ units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of $Cr^{3+}$ and $O^{2-}$ is 62 pm and 140 pm respectively.

Converting them into cm:

$1 pm=10^{-10}cm$

Thus,

$r_{Cr^{3+}}=6.2\times 10^{-9}cm$

and,

$r_{O^{2-}}=1.4\times 10^{-8}cm$

Volume of sphere will be sum of volume of total number of cations and anions thus,

$V_{S}=V_{Cr^{3+}}+V_{O^{2-}}$

Since, volume of sphere is $V=\frac{4}{3}\pi r^{3}$ ,

$V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )$

Putting the values,

$V_{S}=36\left ( \frac{4}{3}(3.14) (6.2\times 10^{-9} cm)^{3}} \right )+54\left ( \frac{4}{3}(3.14) (1.4\times 10^{-8} cm)^{3}} \right )=6.6\times 10^{-22}\times 10^{-8}cm^{3}$

The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

$packing factor=\frac{V_{S}}{V_{C}}=\frac{6.6\times 10^{-22}cm^{3}}{8.7\times 10^{-22}cm^{3}}=0.758$

Thus, atomic packing factor is 0.758.

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Magnesium carbonate and sulphuric acid react to form​

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