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Kitty [74]
3 years ago
11

Pls help me in this:(​

Chemistry
1 answer:
antiseptic1488 [7]3 years ago
3 0

Answer:

a) 26.98

b) 3

c) 3* 1.01 = 3.03

d) 3 *16 = 48

e) 26.98 + 3.03 + 48 = 78.01

f) 6.023 * 10²³

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Promethium-147 is sometimes used in luminescent paint. It has a half-life of 956.3 days. If 250 grams (g) of promethium-147 is u
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Answer:

% = 76.75%

Explanation:

To solve this problem, we just need to use the expressions of half life and it's relation with the concentration or mass of a compound. That expression is the following:

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Where:

A and A₀: concentrations or mass of the compounds, (final and initial)

k: constant decay of the compound

t: given time

Now to get the value of k, we should use the following expression:

k = ln2 / t₁/₂   (2)

You should note that this expression is valid when the reaction is of order 1 or first order. In this kind of exercises, we can assume it's a first order because we are not using the isotope for a reaction.

Now, let's calculate k:

k = ln2 / 956.3

k = 7.25x10⁻⁴ d⁻¹

With this value, we just replace it in (1) to get the final mass of the isotope. The given time is 1 year or 365 days so:

A = 250 e^(-7.25x10⁻⁴ * 365)

A = 250 e^(-0.7675)

A = 191.87 g

However, the question is the percentage left after 1 year so:

% = (191.87 / 250) * 100

<h2>% = 76.75%</h2><h2>And this is the % of isotope after 1 year</h2>
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Phosphorus pentachloride decomposes according to this equation. PCl5(g) equilibrium reaction arrow PCl3(g) + Cl2(g) An equilibri
melisa1 [442]

Answer:

PCl₅ = 0.03 X 208 = 6.24g

PCl₃ = 0.05 X 137 =6.85 g

Cl₂ = 0.03X71 = 2.13 g

Explanation:

The equilibrium constant will remain the same irrespective of the amount of reactant taken.

Let us calculate the equilibrium constant of the reaction.

Kc=\frac{[PCl_{3}][Cl_{2}]}{[PCl_{5}]}

Let us calculate the moles of each present at equilibrium

moles=\frac{mass}{molarmass}

molar mass of PCl₅=208

molar mass of PCl₃=137

molar mass of Cl₂=71

moles of PCl₅ = \frac{mass}{molarmass}=\frac{4.13}{208}=0.02

moles of PCl₃= \frac{mass}{molarmass}=\frac{8.87}{137}=0.06

moles of Cl₂ = \frac{mass}{molarmass}=\frac{2.90}{71}=0.04

the volume is 5 L

So concentration will be moles per unit volume

Putting values

Kc = \frac{\frac{0.06}{5}\frac{0.04}{5}}{\frac{0.02}{5}}=0.024

Now if the same moles are being transferred in another beaker of volume 2L then there will change in the concentration of each as follow

                PCl_{5}--->PCl_{3}+Cl_{2}

Initial                 0.02           0.06       0.04

Change             -x                   +x          +x

Equilibrium     0.02-x           0.06+x    0.04+x

Conc.                (0.02-x)/2       (0.06+x)/2   (0.04+x)/2

Putting values

0.024 = \frac{(0.06+x)(0.04+x)}{(0.02-x)2}

Solving

(0.024(2)(0.02-x)=(0.06+x)(0.04+x)

0.00096-0.048x=0.0024+x^{2}+0.1x

0.148x+x^{2}+0.00144=0

x = -0.01

so the new moles of

PCl₅ = 0.02 + 0.01  =0.03

PCl₃ = 0.06-0.01 = 0.05

Cl₂ = 0.04-0.01 = 0.03

mass of each will be:

mass= moles X molar mass

PCl₅ = 0.03 X 208 = 6.24g

PCl₃ = 0.05 X 137 =6.85 g

Cl₂ = 0.03X71 = 2.13 g

5 0
3 years ago
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