Answer:
CH₃CH₂CH₂COOH > CH₃CH₂COOH > ClCH₂CH₂COOH > ClCH₂COOH
Explanation:
Electron-withdrawing groups (EWGs) increase acidity by inductive removal of electrons from the carboxyl group.
Electron-donating groups (EDGs) decrease acidity by inductive donation of electrons to the carboxyl group.
- The closer the substituent is to the carboxyl group, the greater is its effect.
- The more substituents, the greater the effect.
- The effect tails off rapidly and is almost zero after about three C-C bonds.
CH₃CH₂-CH₂COOH — EDG — weakest — pKₐ = 4.82
CH₃-CH₂COOH — reference — pKₐ = 4.75
ClCH₂-CH₂COOH — EWG on β-carbon— stronger — pKₐ = 4.00
ClCH₂COOH — EWG on α-carbon — strongest — pKₐ = 2.87
Answer:
713.51 N/m
Explanation:
Hook's Law: This law states that provided the elastic limit is not exceeded, the extension in an elastic material is directly proportional to the applied force.
From hook's law,
F = ke ...........................Equation 1
Where F = Force exerted on the bowstring, e = Extension/compression of the bowstring, k = Spring constant of the bow.
Make k the subject of the equation,
k = F/e ............................ Equation 2
Given: F = 264 N, e = 0.37 m.
Substitute into equation 2
k = 264/0.37
k = 713.51 N/m
Hence the spring constant of the bow = 713.51 N/m
Answer:
Percent error = 25%
Explanation:
Given data:
Measured density of water = 1.25 g/mL
Accepted density value of water = 1 g/mL
Percent error = ?
Solution:
Formula:
Percent error = (measured value - accepted value / accepted value) × 100
Now we will put the values in formula:
Percent error = (1.25 g/mL - 1 g/mL /1 g/mL )× 100
Percent error = (0.25 g/mL /1 g/mL )× 100
Percent error = 0.25 × 100
Percent error = 25%
Answer:
Soluble salts can be made by reacting acids with soluble or insoluble reactants. Titration must be used if the reactants are soluble. Insoluble salts are made by precipitation reactions.
Making insoluble salts
An insoluble salt can be prepared by reacting two suitable solutions together to form a precipitate.
Determining suitable solutions
All nitrates and all sodium salts are soluble. This means a given precipitate XY can be produced by mixing together solutions of:
X nitrate
sodium Y
For example, to prepare a precipitate of calcium carbonate:
X = calcium and Y = carbonate
mix calcium nitrate solution and sodium carbonate solution together
calcium nitrate + sodium carbonate → sodium nitrate + calcium carbonate
Ca(NO3)2(aq) + Na2CO3(aq) → 2NaNO3(aq) + CaCO3(s)
It also works if potassium carbonate solution or ammonium carbonate solution is used instead of sodium carbonate solution. Remember that all common potassium and ammonium salts are soluble.
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Explanation:
Answer : The partial pressure of the
in the tank in psia is, 32.6 psia.
Explanation :
As we are given 75 %
and 25 %
in terms of volume.
First we have to calculate the moles of
and
.


Now we have to calculate the mole fraction of
.


Now we have to calculate the partial pressure of the
gas.


conversion used : (1 Kpa = 0.145 psia)
Therefore, the partial pressure of the
in the tank in psia is, 32.6 psia.