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katovenus [111]
3 years ago
15

K for enolization of 2,4-cyclohexadienone is about 1013. Explain why the enol is so much more stable than the keto tautomer.

Chemistry
1 answer:
torisob [31]3 years ago
4 0

Answer:

Because the value of K is huge.

Explanation:

The tautomer is a kind of isomer in which exist an equilibrium between a ketone and an enol, or between an aldehyde and an enol. So, in the enolization, the ketone is the reactant and the enol is the product.

The equilibrium reaction can be characterized by an equilibrium constant, which is the ratio of the concentration of the products by the concentration of the reactants.

Because the constant K is extremely large (10¹³) we can conclude that the concentration of the product will be greater than the concentration of the reactant, in the equilibrium. It means that the concentration of the enol will be greater.

So, the ketone is unstable and forms in a great amount the more stable product, the enol.

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AVprozaik [17]

Answer:

The answer is b

Explanation:

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8 0
2 years ago
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What is the pH of a mixture of 0.042 M NaH2PO4 and 0.058 M Na2HPO4? Hint: The pKa of phosphate is 6.86.
AlekseyPX

Answer:

The pH value of the mixture will be 7.00

Explanation:

Mono and disodium hydrogen phosphate mixture act as a buffer to maintain pH value around 7. Henderson–Hasselbalch equation is used to determine the pH value of a buffer mixture, which is mathematically expressed as,

pH=pK_{a} + log(\frac{[Base]}{[Acid]})

According to the given conditions, the equation will become as follow

pH=pK_{a} + log(\frac{[Na_{2}HPO_{4} ]}{[NaH_{2}PO_{4}]})

The base and acid are assigned by observing the pKa values of both the compounds; smaller value means more acidic. NaH₂PO₄ has a pKa value of 6.86, while Na₂HPO₄ has a pKa value of 12.32 (not given, but it's a constant). Another more easy way is to the count the acidic hydrogen in the molecular formula; the compound with more acidic hydrogens will be assigned acidic and vice versa.

Placing all the given data we obtain,

pH=6.86 + log(\frac{0.058}{0.042})

pH=7.00

5 0
3 years ago
Complete and balance the molecular equation, including the phases, for the reaction of aqueous potassium sulfate, k2so4, and aqu
Tju [1.3M]
The reaction between K₂SO₄(aq) and SrI₂(aq) produces KI(aq) and SrSO₄(s) as products. 

The reaction is 
K₂SO₄(aq) + SrI₂(aq) → KI(aq)+ SrSO₄(s) 

To balance the equation both side of the reaction should have same number of atoms in each element.

Right hand side of the reaction has 1 K, 1 I, 1 Sr, 1 S and 4 O atoms while 2 K, 2 I, 1 Sr,1 S and 4 O present in left hand side of the reaction. 
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Hence, the balanced reaction equation is
K₂SO₄(aq) + SrI₂(aq) → 2KI(aq)+ SrSO₄(s) 
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3 years ago
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Answer:

Explanation:

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STEP 4: FORMATION OF ATP - The high energy generated from the electron transfer process or chain is used to add a phosphate group to ADP (Adenosine dphosphate) to form ATP.

DARK PHASE :In this phase of photosynthesis,the NADPH generated in the light phase is used as a reducing equivalent to reduce CO2 to form Glucose (food) using the ATP generated as a source of energy.

7 0
3 years ago
The atomic number of an element gives the number of __ and __in the atom while the mass number gives the total number of__and__
posledela
The atomic number of an element gives the proton and electron in the atom while the mass number gives the total number of protons and neutron
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