The less soluble salt : PbCl₂
<h3>Further explanation</h3>
Given
0.1 M NaCl
Required
The less soluble salt
Solution
If we see from the answer option, the salt that is more difficult to dissolve in NaCl is PbCl₂ because it has the same ion (Cl)
When PbCl₂ is dissolved in water, ionization will occur
PbCl₂ ⇒ Pb²⁺+ 2Cl⁻
So, when dissolved in NaCl, NaCl itself will be ionized
NaCl ⇒ Na⁺ + Cl⁻
Based on the principle of equilibrium, the addition of an ion (one of the ions is enlarged), the reaction will shift towards the ion that was not added. In addition to this Cl ion, the reaction will shift to the left so that the solubility of PbCl₂ will decrease (the reaction to the right decreases)
If temperature were to double the pressure would likewise double. Increased temperature would increase the energy of the molecules and the number of collisions would also increase causing the increase in pressure.
In the crystallization process the solid compound is dissolved in the solvent at elevated temperature and the crystallize product obtained by slow cooling of the solution. Here the solubility of acetanilide at 100°C is 1g per 20mL of water. Thus to dissolve 500mg of acetanilide at high temperature that is 100°C we need 10mL of water.
Now at 25°C after the re-crystallization there will be some amount of dissolve acetanilide. Which can be calculated as- 185mL of water is needed to dissolve 1g or 1000mg of acetanilide at 25°C. Thus in 10mL of water there will be 
gmg of acetanilide.
Answer:
ΔG = -61.5 kJ/mol (<u>Spontaneous process</u>)
Explanation:
2 NO (g) + O₂ (g) ⇄ 2NO₂ (g)
Let's apply the thermodynamic formula to calculate the ΔG
ΔG = ΔG° + R .T . lnQ
We don't know if the gases are at equilibrium, that's why we apply Q (reaction quotient)
ΔG = - 69 kJ/mol + 8.31x10⁻³ kJ/K.mol . 298K . ln Q
How can we know Q? By the partial pressures (Qp)
P NO = 0.450atm
PO₂ = 0.1 atm
PNO₂ = 0.650 atm
Qp = [NO₂]² / [NO]² . [O₂]
Qp = 0.650² / 0.450² . 0.1 = 20.86
ΔG = - 69 kJ/mol + 8.31x10⁻³ kJ/K.mol . 298K . ln 20.86
ΔG = -61.5 kJ/mol (<u>Spontaneous process</u>)
