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3 years ago

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A

1 answer:

DanielleElmas [232]3 years ago

3 0

B. because if you add ice to tea and water it decreases the temperature as the ice melts

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3 years ago

What is the percent yield of NaCl if 31.0 g of CuCl2 reacts with excess NaNO3 to produce 21.2 g of NaCl?

Harrizon [31]

First you need to find the balanced chemical formula.
CuCl₂+2NaNO₃→2NaCl+Cu(NO₃)₂

Then you can find out how much NaCl 31.0g of CuCl₂ should produce using stoichiometry. Divide 31.0g by the molar mass of CuCl₂ (134.446g/mol) to get 0.2306mol CuCl₂. Than multiply 0.2306mol CuCl₂ by 2 to get 0.4612mol NaCl. Than multiply 0.4612mol by the molar mass of NaCl (58.45g/mol) to get 26.95g of NaCl.
that means that 100% yield would give you 26.95g of NaCl so to find percent yield divide 21.2 by 26.95 to get 0.7867 which is 78.7% yield

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3 0

3 years ago

A voltaic cell consists of a Zn>Zn2+ half-cell and a Ni>Ni2+ half-cell at 25 °C. The initial concentrations of Ni2+ and Zn

nlexa [21]

Answer :

(a) The initial cell potential is, 0.53 V

(b) The cell potential when the concentration of $Ni^{2+}$ has fallen to 0.500 M is, 0.52 V

(c) The concentrations of $Ni^{2+}$ and $Zn^{2+}$ when the cell potential falls to 0.45 V are, 0.01 M and 1.59 M

Explanation :

The values of standard reduction electrode potential of the cell are:

$E^0_{[Ni^{2+}/Ni]}=-0.23V$

$E^0_{[Zn^{2+}/Zn]}=-0.76V$

From this we conclude that, the zinc (Zn) undergoes oxidation by loss of electrons and thus act as anode. Nickel (Ni) undergoes reduction by gain of electrons and thus act as cathode.

The half reaction will be:

Reaction at anode (oxidation) : $Zn\rightarrow Zn^{2+}+2e^-$ $E^0_{[Zn^{2+}/Zn]}=-0.76V$

Reaction at cathode (reduction) : $Ni^{2+}+2e^-\rightarrow Ni$ $E^0_{[Ni^{2+}/Ni]}=-0.23V$

The balanced cell reaction will be,

$Zn(s)+Ni^{2+}(aq)\rightarrow Zn^{2+}(aq)+Ni(s)$

First we have to calculate the standard electrode potential of the cell.

$E^o=E^o_{cathode}-E^o_{anode}$

$E^o=E^o_{[Ni^{2+}/Ni]}-E^o_{[Zn^{2+}/Zn]}$

$E^o=(-0.23V)-(-0.76V)=0.53V$

(a) Now we have to calculate the cell potential.

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Zn^{2+}]}{[Ni^{2+}]}$

where,

n = number of electrons in oxidation-reduction reaction = 2

$E_{cell}$ = emf of the cell = ?

Now put all the given values in the above equation, we get:

$E_{cell}=0.53-\frac{0.0592}{2}\log \frac{(0.100)}{(1.50)}$

$E_{cell}=0.49V$

(b) Now we have to calculate the cell potential when the concentration of $Ni^{2+}$ has fallen to 0.500 M.

New concentration of $Ni^{2+}$ = 1.50 - x = 0.500

x = 1 M

New concentration of $Zn^{2+}$ = 0.100 + x = 0.100 + 1 = 1.1 M

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Zn^{2+}]}{[Ni^{2+}]}$

Now put all the given values in the above equation, we get:

$E_{cell}=0.53-\frac{0.0592}{2}\log \frac{(1.1)}{(0.500)}$

$E_{cell}=0.52V$

(c) Now we have to calculate the concentrations of $Ni^{2+}$ and $Zn^{2+}$ when the cell potential falls to 0.45 V.

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Zn^{2+}+x]}{[Ni^{2+}-x]}$

Now put all the given values in the above equation, we get:

$0.45=0.53-\frac{0.0592}{2}\log \frac{(0.100+x)}{(1.50-x)}$

$x=1.49M$

The concentration of $Ni^{2+}$ = 1.50 - x = 1.50 - 1.49 = 0.01 M

The concentration of $Zn^{2+}$ = 0.100 + x = 0.100 + 1.49 = 1.59 M

5 0

4 years ago