When light travels from a medium with higher refractive index into a medium with lower refractive index, there is a maximum angle (called critical angle) for which all the light is reflected, so there is no refraction.
The value of the critical angle is given by:

when n1 is the refractive index of the first medium, while n2 is the refractive index of the second medium. In our case, n1=1.33 (the water) and n1=1.00 (the air). Putting numbers in, we get
Answer:
Velocity = 4.33[m/s]
Explanation:
The total energy or mechanical energy is the sum of the potential energy plus the kinetic energy, as it is known the velocity and the height, we can determine the total energy.
![E_{M}=E_{p} + E_{k} \\E_{p} = potential energy [J]\\E_{k} = kinetic energy [J]\\where:\\E_{p} =m*g*h\\E_{p} = 4*9.81*0.5=19.62[J]\\E_{k}=\frac{1}{2} *m*v^{2} \\E_{k}=\frac{1}{2} *4*(3)^{2} \\E_{k}=18[J]\\Therefore\\E_{M} =18+19.62\\E_{M}=37.62[J]](https://tex.z-dn.net/?f=E_%7BM%7D%3DE_%7Bp%7D%20%20%2B%20E_%7Bk%7D%20%5C%5CE_%7Bp%7D%20%3D%20potential%20energy%20%5BJ%5D%5C%5CE_%7Bk%7D%20%3D%20kinetic%20energy%20%5BJ%5D%5C%5Cwhere%3A%5C%5CE_%7Bp%7D%20%3Dm%2Ag%2Ah%5C%5CE_%7Bp%7D%20%3D%204%2A9.81%2A0.5%3D19.62%5BJ%5D%5C%5CE_%7Bk%7D%3D%5Cfrac%7B1%7D%7B2%7D%20%2Am%2Av%5E%7B2%7D%20%20%5C%5CE_%7Bk%7D%3D%5Cfrac%7B1%7D%7B2%7D%20%2A4%2A%283%29%5E%7B2%7D%20%5C%5CE_%7Bk%7D%3D18%5BJ%5D%5C%5CTherefore%5C%5CE_%7BM%7D%20%3D18%2B19.62%5C%5CE_%7BM%7D%3D37.62%5BJ%5D)
All this energy will become kinetic energy and we can find the velocity.
![37.62=\frac{1}{2} *m*v^{2} \\v=\sqrt{\frac{37.62*2}{4} } \\v=4.33[m/s]](https://tex.z-dn.net/?f=37.62%3D%5Cfrac%7B1%7D%7B2%7D%20%2Am%2Av%5E%7B2%7D%20%5C%5Cv%3D%5Csqrt%7B%5Cfrac%7B37.62%2A2%7D%7B4%7D%20%7D%20%5C%5Cv%3D4.33%5Bm%2Fs%5D)
Electron configurations:
Ge: [Ar] 3d10 4s2 4p2 => 6 electrons in the outer shell
Br: [Ar] 3d10 4s2 4p5 => 7 electrons in the outer shell
Kr: [Ar] 3d10 4s2 4p6 => 8 electrons in the outer shell
The electron affinity or propension to attract electrons is given by the electronic configuration. Remember that the most stable configuration is that were the last shell is full, i.e. it has 8 electrons.
The closer an atom is to reach the 8 electrons in the outer shell the bigger the electron affinity.
Of the three elements, Br needs only 1 electron to have 8 electrons in the outer shell, so it has the biggest electron affinity (the least negative).
Ge: needs 2 electrons to have 8 electrons in the outer shell, so it has a smaller (more negative) electron affinity than Br.
Kr, which is a noble gas, has 8 electrons and is not willing to attract more electrons at all, the it has the lowest (more negative) electron affinity of all three to the extension that really the ion is so unstable that it does not make sense to talk about a number for the electron affinity of this atom.