Answer:
Molar heat of solution of KBr is 20.0kJ/mol
Explanation:
Molar heat of solution is defined as the energy released (negative) or absorbed (Positive) per mole of solute being dissolved in solvent.
The dissolution of KBr is:
KBr → K⁺ + Br⁻
In the calorimeter, the temperature decreases 0.370K, that means the solution absorbes energy in this process. The energy is:
q = 1.36kJK⁻¹ × 0.370K
q = 0.5032kJ
Moles of KBr in 3.00g are:
3.00g × (1mol / 119g) = 0.0252moles
Thus, molar heat of solution of KBr is:
0.5032kJ / 0.0252moles = <em>20.0kJ/mol</em>
Answer:
Final molarity of iodide ion C(I-) = 0.0143M
Explanation:
n = (m(FeI(2)))/(M(FeI(2))
Molar mass of FeI(3) = 55.85+(127 x 2) = 309.85g/mol
So n = 0.981/309.85 = 0.0031 mol
V(solution) = 150mL = 0.15L
C(AgNO3) = 35mM = 0.035M = 0.035m/L
n(AgNO3) = C(AgNO3) x V(solution)
= 0.035 x 0.15 = 0.00525 mol
(AgNO3) + FeI(3) = AgI(3) + FeNO3
So, n(FeI(3)) excess = 0.00525 - 0.0031 = 0.00215mol
C(I-) = C(FeI(3)) = [n(FeI(3)) excess]/ [V(solution)] = 0.00215/0.15 = 0.0143mol/L or 0.0143M
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