Answer:

Explanation:
Hello there!
In this case, according to the given information, it turns out necessary for us remember that the first-order kinetics is given by:

Whereas the 27.5% complete means A/Ao=0.275, and thus, we solve for the rate constant as follows:

Then, we plug in the variables to obtain:

Regards!
This question is more for Biology than Chemistry, but the role of producers is to make energy (food) to be consumed. In a pyramid diagram, the producers would be at the bottom. Now going up the pyramid, the primary conumers are the first to consume producers and obtain energy from them. As you go up the pyramid, the secondary consumers will consume the primary consumers as a way to obtain energy, and the same goes for tertiary consumers towards secondaries.
As you go up the energy pyramid, you will notice a trend that there is less energy being obtained from each consumer. In other words, the producers will ALWAYS have more energy than the tertiary consumers.
I hope this answers your question.
if i am correct the volume of nitrogen gas has to equal to molecules density, making the substance 1.27 liters :)